自由基聚合反应

烯类单体在室温离子液体中的自由基聚合反应研究进展

Progress in Free Radical Polymerization of Vinyl Monomers in Room Temperature Ionic Liquids

结果表明铜离子介入的MMA在BSA上的接枝聚合属于自由基聚合反应，并表现出乳液聚合的特征。

The results reveal that copper mediated graft copolymerization of MMA on BSA is free radical polymerization , similar to an emulsion polymerization .

自由基聚合反应的MonteCarlo模拟方法

Monte Carlo Simulation Method of Radical Polymerization

本文以丙烯酰胺（AM）和丙烯酰氧基乙基三甲基氯化胺（ADAMQUAT）为共聚单体，通过自由基聚合反应合成阳离子聚丙烯酰胺（CPAM）。

In the paper , the cationic polyacrylamide ( CPAM ) was synthesized with comonomers of acrylamide ( AM ) and acryloyloxyethyl trimethylammonium chloride ( ADAMQUAT ) by radical polymerization .

采用过渡金属催化原子转移自由基聚合反应的方法，合成了高支化聚苯乙烯（HBPS）；

High branched PS ( HBPS ) was synthesized by means of metal-catalyzed living radical polymerization .

采用水解缩合法合成了八乙烯基笼型POSS，通过一般自由基聚合反应合成了聚甲基丙烯酸甲酯（PMMA）、聚对乙酰氧基苯乙烯（PAS）和聚苯乙烯（PS）。

Octa-vinyl polyhedral oligomeric silsesquioxane ( POSS ) was synthesized by hydrolyze-condensation method . PMMA , PAS and PS were synthesized by a conventional free radical polymerization technique under nitrogen using a vacuum-line system .

第二章，首次将DTA用于自由基聚合反应，提出了DTA还原过程为两步单电子转移，能够引发自由基聚合的机理。

Chapter II : It is the first time that DTA was employed in radical polymerization . A two-step single-electron-transfer process of DTA reductions is proposed to explain the production of free radicals and the initiation .

提取乙烯裂解副产物C5馏分中的双环戊二烯馏分，与裂解C9、C5馏分按不同配比混合，通过自由基聚合反应得到热聚型石油树脂，并确定了热聚型石油树脂的工艺参数。

DCPD extracted from the by-product Cs of ethylene cracking blends with cracked C9 fraction , C5 fraction . and then the petroleum resin can be produced through free radical polymerization reaction , and the process parameter for petroleum resin of the thermal polymerization after reaction .

红外光谱原位跟踪活性自由基聚合反应过程研究

Study of " Living " Radical Polymerization by FTIR in Situ

表面引发原子转移自由基聚合反应制备有机/无机复合材料

Fabrication of Organic / Inorganic Hybrid Composites by Surface-Initiated Atom Transfer Radical Polymerization

铁（Ⅱ）/衣糠酸催化体系应用于原子转移自由基聚合反应的研究

Study of Atom Transfer Radical Polymerization Mediated by Iron ~ⅱ Chloride / Itaconic Acid

研究了采用过氧引发基团的表面引发反向原子转移自由基聚合反应。

( 3 ) The surface-initiated reverse atom transfer radical polymerization was also studied .

自由基聚合反应动力学的数学建模&多自由基数学模型

Modeling of Free-Radical Polymerization Kinetics & Polyradical Model

以零价铜为催化剂的活性/可控自由基聚合反应

' Living ' / controlled Radical Polymerization by Using Zero valent Copper as Catalysts

引发剂结构对原子转移自由基聚合反应的影响

Effect of the Structures of Initiators on the Atom Transfer Radical Polymerization of Styrene

自由基聚合反应介观模拟

Mesoscopic Simulation of Free - radical Polymerization Reaction

探讨了这种活性自由基聚合反应机理。

This living radical photopolymerization mechanism was explained .

活性自由基聚合反应合成超支化聚苯乙烯及其性能研究

Studies on the preparation and properties of hyper - branched polystyrene from living radical polymerization

原子转移自由基聚合反应在合成预定结构聚合物中的应用

The application of atom transfer free radical POLYMERI-ZATION to preparation of polymers with various structure

在自由基聚合反应中，每个聚合物分子都是经历成百上千次加成聚合形成。

In polymerization reaction , each polymer molecule is formed via hundreds and thousands additions .

啮合异向旋转双螺杆挤出机内自由基聚合反应挤出过程的数值模拟

Numerical Simulation of Reactive Extrusion Processes for Free Radical Polymerization in Counter-rotating Twin Screw Extruder

根据分析结果，提出a－蒎烯等离子体聚合机理是自由基聚合反应机理。

According to the analytical results , the mechanism of plasma polymerization of a-pinene is suggested .

乙烯基咪唑是通过自由基聚合反应接枝到硅胶载体上的，得到的是一种大分子配基。

The ligand obtained from VI graft polymerization on silica gel is a kind of polymeric form .

在引发剂的作用下，苯乙烯发生自由基聚合反应，本课题研究了一系列不同结构的引发剂对自由基聚合反应过程的影响。

Free-radical polymerization of styrene was carried out in the presence of a series of peroxide initiators .

介绍了原子转移自由基聚合反应这一新型的活性自由基聚合方式；

Atom transfer free radical polymerization is a kind of new reaction to realized " living " free radical polymerization .

过渡金属盐催化下的MA活性自由基聚合反应

Transition - metal - catalyzed Atom Transfer Radical Polymerization of Methyl Acrylate in the Presence of a Conventional Radical Initiator

研究表明，采用这种方法简便、原料易得的表面引发氮氧自由基聚合反应是一个活性/可控自由基聚合历程。

The experiment results indicated this surface-initiated nitroxide-mediated radical polymerization is a " living " / controllable free radical polymerization .

利用有机单体自由基聚合反应机制，采用聚合物网络法制备了纳米氧化锡粉体。

SnO_2 nanopowders were prepared by polymer network method based on principle of free-radical polymerization of organic monomers with stannic chloride as starting material .

多环芳烃在高分子液晶柱上的保留行为3在丙烯酰化硅胶表面发生自由基聚合反应，得到用于高效液相色谱柱的新型高分子手性固定相。

Retention Behaviours of PAHs on Liquid Crystalline Polymer Stationary Phases Novel chiral polymer stationary phases were prepared by free-radical polymerization of 3 on silica gel .

基于自由基聚合反应的机理，采用双水相聚合方式及交联技术，合成了网状的阳离子聚丙烯酰胺水包水乳液。

Based on the radical reaction theory , it is recognized that network CPAM should be synthesized by adopting aqueous biphasic polymerization system and cross-linking technology .