基体改进剂
- 网络matrix modifier;Chemical Modifier
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痕量分析研究为锡筛选出最佳基体改进剂,硝酸锶可使锡的允许灰化温度明显提高,灵敏度和检出限分别改善45倍和51倍,显著优于文献报道值。
Sodium strontium was chose as the chemical modifier in the trace analysis of tin , which caused the highest allowable temperature enhanced obviously . The characteristic mass and detection limit was improved 45 and 51 folds .
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采用钯,钯-镁作基体改进剂,FIA-HG-GFAAS法成功地测定了锗。
Germanium was successfully determined by FIA-HG-GFAAS with matrix modifiers Pd and Pd-Mg .
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测定时用Mg(NO3)2作基体改进剂。
Mg ( NO_3 ) _2 was used as a matrix modifier in determination of beryllium .
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X-100为基体改进剂.用石墨炉原子吸收法直接测定血清中砷、硒.该法具有操作简单、快速、灵敏度高的特点,为临床测定血清小砷、硒提供了一种新方法。
The method is simple , rapid and highly sensitive . It 's a new method for chinical determination of arsenic and selenium in serum .
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用混合基体改进剂石墨炉AAS测定矿石中的锗
Determination of Germanium in Geological Samples by Graphite Furnace AAS Using Mixed Matrix Modifier
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钯作基体改进剂FIA-HG-GFAAS法测定锗及其机理研究
Determination of Germanium by FIA-HG-GFAAS with the Matrix Modifier Palladium and Its Mechanism
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通过对照硅在热解石墨管、涂钼及涂钨石墨管中的原子化行为,选用涂钼石墨管和La做基体改进剂,石墨炉原子吸收法测定铝矾土中的硅。
In this paper , atomization behaviors of Si in pyro coated , molybdenum coated and tungsten coated graphite tubes are evaluated and compared .
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结论:有机基体改进剂可有效消除GFAAS测定补钙食品中Pb和Cd的基体干扰。
Conclusion : Organic matrix modifiers can eliminate matrix interference when determine Pb and Cd in supplementary calcium food by GFAAS effectively .
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GFAAS中有机基体改进剂消除食盐基体干扰的研究
Study of Organic Matrix Modifiers for Elimination of Salt Matrix Interference in GFAAS
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对于钙作基体改进剂的方法,Ar-5%H2替代Ar作保护气氛有利于降低背景吸收。
Using Ca as the matrix modifier , Ar-5 % H_2 in place of Ar as the purge gas was advantageous to reducing the background .
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重点介绍了用电热原子吸收法测Ga时,基体改进剂、进样方式以及预富集技术对提高方法灵敏度的作用。
Emphasis is given to the improvement of sensitivity of Ga by electrothermal AAS through the use of matrix modification , sampling mode and preconcentration technique .
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基体改进剂在GFAAS法测定酱油铅含量中的应用研究
Study of matrix modifiers for determination of lead content in soy sauce in GFAAS
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以Pd为基体改进剂,建立了浮体制样石墨炉原子吸收光谱法直接测定煤中微量As的方法。
A method for direct determination of trace arsenic in coal by slurry-sampling Graphite-Furnace Atomic Absorption Spectrometry ( GFAAS ) was developed , using Pd as a matrix modifier .
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标准加入法-抗坏血酸基体改进剂GFAAS测定腐乳中痕量铅
Determination of trace Pb in sufu by GFAAS using standard addition method and ascorbic acid as matrix modifier
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有机基体改进剂消除GFAAS测定补钙食品中铅和镉干扰的研究
The study of organic matrix modifiers for the elimination of interference when determinate Pb and Cd in supplementary calcium food by GFAAS
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比较了多种涂层金属处理石墨管和多种基体改进剂对GFAAS法测定微量铍的影响。
Different kinds of coating layers and matrix modifiers have been tested for the determination of trace beryllium in biological samples by GFAAS .
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采用热解涂层石墨管,应用氘灯扣除背景技术,在无任何基体改进剂的条件下,提出连续测定沱江河水中Cu、Pb、Cd、Cr的方法。
The continuous determination of copper , lead , cadmium , chromium in Tuojiang river is described in this paper by using pyrolytic coating graphite tube under the technique of BGC D2 background correction without any other matrix modifiers .
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本文经过深入研究提出了用HNO3H2O2消化样品,以钯盐作基体改进剂,用石墨炉原子吸收测定矿泉水的Pb,Cr的分析方法。
A method of determination of lead and chromium in mineral water by graphite furnace atomic absorption spectrometry has been advanced . HNO 3 H 2O 2 was used to digest the samples and the palladic salt as a matrix improver .
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系统研究了用石墨炉原子吸收光谱法测定八种植物染发剂中Pb、Cd和Cu的仪器测定条件,包括干燥温度、灰化温度、原子化温度、基体改进剂等,得到最佳仪器测定条件。
Apparatus conditions of GFAAS for determination of Pb . Cd and Cu in eight kinds of plant hair dyes were inquired . The factors affecting the result were investigated including the drying temperature , atomization temperature , ashing temperature and matrix modifier .
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本文采用基体改进剂NH4NO3&HNO3体系与涂镧石墨管相结合的方法,消除了无焰原子吸收法的干扰现象。该法可用于测定工业废水及真菌中的铅。
In this paper , a method of combining matrix modifier NH_4NO_3-HNO_3 with La-plaster graphite tube may remove the interference phenomenon and can be used to determine lead in industry waste water and fungus .
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试验了(NH4)2HPO4,NH4H2PO4、Na2HPO4、Mg(NO3)2和Pd作为石墨炉原子吸收测定全血铅基体改进剂的作用效果。
A simple and rapid method for the direct determination of Pb in blood by Graphite Furnace Atomic Absorption Spectrometry is described . To eliminate the blood matrix interferences ,( NH_4 ) _2HPO_4 and Na_2HPO_4 have been selected as the matrix modifier .
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本文研究了以KNO3作基体改进剂,用标准加入法、光控温度石墨炉原子吸收光谱法直接测定了人体血液中痕量锡。
In this paper , the determination of trace tin in blood by optical temperature control GFAAS with the use of KNO_3 as matrix modifier was studied .
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目的:用有机试剂为基体改进剂来消除GFAAS测定食盐中铅的背景吸收和基体干扰,建立有机基体改进剂GFAAS测定食盐中铅的方法。
Objective : To develop a method for determination of lead in salt by GFAAS using organic reagent as matrix modifier , which could eliminate the background Absorb and matrix interference produced by NaCl .
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选择HNO3-H2O2试测进行前处理,于样品消解前加入镍为基体改进剂,使鱼中砷的加标回收率达97%,检出下限为4μg/kg。
The samples were treated with HNO_3-H_2O_2 and Ni as matrix modifier was put before the samples were dissolved . The recovery was 97 % . The limit of detection was 4 μ g / kg .
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研究石墨炉原子吸收法测定土壤中有效钼,采用超声波溶样,APDC-MIBK萃取,抗坏血酸作基体改进剂。
Available molybdenum in soil was determined by graphite furnace atomic absorption after supersonic dissolving and APDC-MIBK extraction . Ascorbic acid was used as matrix modifier .
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用NH4NO3-Pb(N03)2联合基体改进剂,石墨炉法直接测定地面水中的痕量镉。
Determination of trace lead in groundwater sample by furnace atomic absorption spectroscopy With NH_4NO_3-Pb ( NO_3 ) _2 matrix-modifier combine .
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在MD-GFAAS中,对待测元素前处理条件、仪器参数、石墨炉升温程序和基体改进剂进行了优化和筛选。
In MD-GFAAS , pre-treatment conditions , instrument parameters , temperature program of GFAAS and the addition of matrix modifiers were optimized .
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研究了多种基体改进剂消除蚝油基体对测铅的干扰,方法的相对标准偏差为4.9%,回收率为94%-96%,检出限为1.5ng/mL。
The method studied varied kinds of modifiers for elimination of the disturbance of oyster sauce matrix in detecting Pb . The detection limit is 1.5ng / mL , recoveries are between 94 % - 96 % , RSD is 4.9 % .
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将面粉与三乙醇胺、水混溶后,在沸水浴中加热3min制成悬浮溶液直接进样测定,以钯作基体改进剂,使灰化温度提高至1200℃,将背景干扰降至仪器能扣除的水平。
Mingling flouts , triethanolamine and water , and heating on water bath for 3 minutes , then slurry samples were introduced to graphite furnace . A matrix modifier Pd was applied to raise the charring temperature to 1200 ℃ .
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试验了集恒温平台石墨炉(STPF)于一体的纵向塞曼效应背景校正,最大功率升温,钯作为基体改进剂和峰面积积分(A-s)测定废水中低含量锡的新方法。
New method to determine low content Tin in wastewater was tested . It combined stable temperature platform graphite furnace , undertook correction with vertical Zeeman effect background , took palladium as matrix modifier and peak area integral .