基元反应步骤
基元反应步骤-
羰基钴催化的氢甲酰化反应循环中乙烯插入、羰基插入、H2氧化加成和脱氢还原的基元反应步骤的活化位垒分别为2.11，16.22、33.03和10.71kcal／mol。
The activation energies of olefin insertion , carbonyl insertion , H2 oxidative addition and aldehyde reductive elimination fundamental steps catalyzed by HCo ( CO ) 3 , are 2.11 , 16.22 , 33.03 and 10.71 kcal / mol , respectively .