轮烷

该轮烷体系中，我们希望随着冠醚环的移动，利用二茂铁和葸荧光团之间的PET过程来影响葸的荧光。

In this rotaxane , we expected that the movement of macrocycle can influence the fluorescence of anthracene fluorophore by the distance-dependent photoinduced electron transfer ( PET ) process between ferrocene and anthracene .

轮烷研究&从超分子组装到分子器件

Rotaxane : From Supramolecular Self - Organization to Molecular Devices

瓜环[2]准轮烷分子晶体结构及切割DNA研究

Crystal Structure and DNA Cleavage of [ 2 ] Pseudorotaxane Composed of Cucurbit [ 6 ] uril

环糊精是多聚（准）轮烷重要的主体化合物之一，环糊精（CD）与大分子间的组装以其选择性、可调控性和生物相容性等优势引起广泛关注。

Cyclodextrins are one of the most important host of poly ( pseudo ) rotaxanes , assembly between cyclodextrine ( CD ) and polymer have attracted growing attention due to their selectivity , regulation and control , and bio-compatibility .

环糊精与高分子组装（准）聚轮烷的影响因素

Influence Factors of Self-Assembling Poly ( pseudo ) rotaxanes with Cyclodextrins

三联吡啶钌配合物为端基的共轭金属轮烷的合成及性质研究

Conjugated Rotaxanes with Bis-terpyridyl Ruthenium Complex as End Group : Synthesis , Characterization and Properties

综述了近年来轮烷类化合物的合成原理、合成方法及其应用等方面的研究进展。

This review introduces the synthesis theory , procedure of the rotaxanes and their applications as well .

环糊精（准）聚轮烷是由环糊精与链状高分子通过非共价键结合得到的超分子结构。

It was dealed with the various influence factors of self-assembling poly ( pseudo ) rotaxanes with cyclodextrins .

轮烷化合物是研究分子开关和分子马达等超分子器件的模型化合物之一。

Rotaxanes can be used as the model compounds of supramolecule devices , such as molecule switch and molecule motor .

目前阴离子诱导分子自组装主要应用于合成螺旋和轮烷结构化合物、大环化合物、分子识别等领域。

Currently , anion-induced molecular self-assembly is mainly used in the synthesis of helices and rotaxane structure compound , macrocyclic compounds , molecular recognition .

轮烷是一类由两端带有大的基团的线性分子和有机环化合物组成的互相锁连的分子化合物。

Rotaxanes are a class of supramolecules in which one or more macrocyclic molecules are threaded by one linear molecule with two big stoppers at its ends .

这其中，互锁系统（比如索烃和轮烷）的合成和研究已成为超分子化学中不可分割的一部分。

Furthermore , the synthesis and the study of interlocked structures ( catenanes and rotaxanes ) has become an unavoidable topic within the field of supramolecular chemistry .

该类大环杯[4]冠醚在作为金属离子载体或作为轮烷、索烃等分子机器的构建单元等方面具有潜在的应用。

This kind of macrocyclic calix [ 4 ] crown ethers can be used as metal ion carrier or as rotaxanes , catenanes , which are the construction modules for molecular machines and has a practical potential .

而含有金属离子或金属配合物的金属轮烷，不仅具有特殊的结构，而且具有电子迁移、能量传递和光、电、磁、机械运动等多种新颖性质。

Rotaxanes , which contain metallic ion or metal complex , not only have special structures , but also possess multiple properties , such as electron transfer , energy transfer , irradiancy , electricity , magnetism and mechanical movement .