反应活化能
- 网络activation energy;activation energy of reaction
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并且进而提出本区低成熟石油的成油下限埋深划分至2800m为宜,其对应的下限反应活化能不超过177KJ/mol。
In addition , it was shown that the deepest burial depth of generating immature oils is about 2800 meters in study area and the corresponding activation energy about 177 KJ / mol.
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用DTA法测得UM树脂、UP树脂、VE树脂的表观固化反应活化能分别为45.5kJ/mol、56.7kJ/mol和75.8J/mol。
The apparent values of the curing activation energy of UM resin , UP resin and VE resin are obtained by DAT method . The results are as follows : 45.5 kJ / mol , 56.7 kJ / mol and 75.8 kJ / mol respectively .
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碳酸盐缓冲溶液吸收CO2反应活化能的脉冲响应法测定
Determination of Activation Energy of CO_2 Absorption in Carbonate Bicarbonate Buffer Solution by Pulse-Response Method
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加勒比松Na2S预处理硫酸盐&AQ蒸煮机理及脱木素反应活化能
The mechanism and delignification activation energy of Na_2S pretreatment Kraft-AQ pulping of Caribbean pine
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微波对Fenton试剂降解苯酚反应活化能的影响
Effect of Microwave on Reaction Activation Energy of Phenol Degradation by Fenton Reagent
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Ni3S2的腐蚀溶出受固体扩散和电荷传递混合控制,反应活化能为11.596kJ/mol。
The reaction rate of Ni_3S_2 corrosion dissolution is controled by the combined processes of solid diffusion and electron charge transfer .
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在相同实验条件下,纳米铁对酸性红B的降解速率比普通铁提高了4.7倍,反应活化能降低了65%。
Under the same conditions , the degradation efficiency of Acid Red B by nano-iron is 4.7 times higher than that by common iron , and the obvious energy of activation reduces by 65 % .
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动力学区域的反应活化能为35.9kJ/mol,内扩散区域的活化能为15.7kJ/mol。
The activation energy of reaction is 35.9kJ/mol in the kinetic region , but 15.7kJ/mol in the internal diffusion region .
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碳还原锆英石的表现反应活化能,在1600~2000℃温度范围内为282.04kJ/mol。
The apparent activation energy for the reaction of zircon with carbon was 282.04 kJ / mol ( 1600 ~ 2000 ℃) .
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反应活化能22-38(平均值:28)kJmol-1。
The activation energy was estimated to be 22-38 ( mean : 28 ) kJ mol-1 .
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热周环反应活化能的HMO计算
HMO Calculation of Activation Energies of Thermal Pericyclic Reactions
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运用Kissinger和Ozawa法进行了动力学研究,得到其固化反应活化能。
Curing reaction kinetic parameters was obtained by data processed by means of Kissinger and Ozawa method .
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AP比表面积的增大会导致推进剂初始分解温度、高低温热分解峰温和高低温下分解反应活化能的降低,但分解反应速度常数随AP比表面积的增大而增大。
The increase of AP specific surface area lead to decrease of initial decomposition temperature , decomposition peak temperature and decomposition activation energy , but reaction rate constant rise .
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现有机械零件参数化CAD系统,有的功能虽然较强,但系统过于庞大,价格高昂,且有待于更新计算机技术.反应活化能较高;集成度高、携带方便等特点。
Currently , machine parts parametrized CAD systems are available in the market . Some of them may be powerful but they are enormous in volume , high in price , and awaiting renewal of computer technique .
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研究结果表明,树脂中引入纳米TiO2,降低了固化反应活化能和树脂固化后处理温度,改善了BMI树脂的加工性能;
The results showed that nanometer sized TiO 2 could decrease the activation energy of curing reaction and post treatment temperature of resin , and improve the processability of BMI .
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在空气中PEEK的热分解显示两个过程,由此计算其在空气中第一阶段的热分解和氮气中的热分解反应活化能分别为214.7kJ/mol和232.2kJ/mol;
The activation energies of the thermal degradation were found to be 232.2 kJ / mol and 214.7 kJ / mol in nitrogen and air , respectively .
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采用差热扫描量热法(DSC)对两种涤纶粘合活化油剂试样的表观反应活化能和反应级数进行了测定,并利用公式计算出油剂的固化反应表观活化能和反应级数。
The apparent activation energy and reaction order of curing process in the PET tire cord activation spin finish were determined by differential scanning calorimetry ( DSC ) and were calculated by formulas .
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讨论了温度、微波功率对总有机碳(TOC)去除率的影响,估算了反应活化能。
The effects of reaction temperature and microwave power on the total organic Carbon ( TOC ) removal were then discussed , and the reaction activation energies were finally estimated .
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对化学镀沉积反应活化能的实验测试表明,由于酸性镀液中采用pK值较低的乳酸作为络合剂,反应体系的活化能较低,镀速较高。
The experimental analysis of activation energy of electroless deposition reaction shows that acidic bath reaction system possesses a low activation energy and a high deposition rate .
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而对于端羟基聚丁二烯/己二异氰酸酯催化剂体系,前后期反应活化能基本一致,为32.1kJ/mol。
And for the HTPB / HDI system with catalyst , the E a value is 32.1 kJ / mol.
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反应活化能估算结果表明,对类Fenton试剂降解苯酚的反应体系施加微波,可降低反应活化能和提高反应速率,微波辐射的功率越大,苯酚转化速率和TOC降解速率就越快。
Results showed that application of microwave radiation can improve the degradation rate and the removal rate of phenol as well as the removal rate of TOC in the heterogeneous Fenton-like reaction .
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Ni-Al-Fe体系热爆反应活化能和反应级数的测定
Measurement of the Activation Energy and Reaction Order of the Ni-Al-Fe System Thermal Explosion
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结果表明,在不同的升温速度及催化剂浓度下,交联反应活化能均在90kJ/mol左右,反应级数n及阿累尼乌斯频率因子lnA也分别在1.2~1.4以及20~22之间。
The experiments indicate that the activation energy is about 90 kJ / mol , and the reaction order and natural log of the frequency factor between 1.2 ~ 1.3 and 20 ~ 22 s - 1 , respectively .
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微波的快速烧结能降低反应活化能并促进晶界的扩散,从而有助于获得高致密度的PLZT陶瓷;
The recent research showed that rapid sintering of microwave sintering reduces the activation-energy and accelerates the diffuse the crystal boundary and help to improve the density of PLZT .
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反应活化能约为7KJ左右。200~240℃时反应的半衰期约在40min左右。
The activity energy is about 7 KJ , and the half life in 200-240 is 40 min.
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通过对中温固化环氧树脂DSC、扭辫分析、凝胶时间、粘度、力学性能的测定,固化反应活化能的计算,研究了在贮存树脂的过程中环境湿度对树脂的固化反应和性能的影响。
Using middle temperature curing epoxy resin , it has been investigated that the effect of humidity to reisn curing and properties in resin storage by the test of DSC , TBA , gel time , viscosity and mechanical properties and the calculation of curing Ea .
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EM体系的热固化反应活化能为84.85KJ/mol,固化反应的反应级数为0.849。
It indicates that the accelerant M is effective on 594 cured epoxy system and the apparent activation energy is 84.85kJ / mol , and the level of the curing reaction is 0 . 849 .
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用Kissinger法和Ozawa-Flynn-Wall法计算出的bis-ANER/DDE非等温固化反应活化能分别为57.6和61.5kJ/mol。
The apparent activation energies of the no-isothermal curing for the bis-ANER / DDE evaluated with the Kissinger and Ozawa-Flynn Wall methods were 57.6 and 61.5 kJ / mol , respectively .
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表面反应活化能及固体扩散活化能分别为58.8kJ/mol及105.73kJ/mol。
The activation energies of surface reaction and solid diffusion were determined as 58.8kJ/mol and 105 . 73kJ / mol , respectively .
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因而实验撞击感度与引发键C-H的键级之间存在平行一致的递变关系,实验撞击感度与热解引发反应活化能之间基本上存在平行一致的递变关系。
So it has a parallel relationship between the experimental impact sensitivity and the bond order of alpha C-H bond . And also it has a parallel relationship between the experimental impact sensitivity and the activation energy of the isomerization reaction .