原子转移自由基聚合

本文对原子转移自由基聚合及其反应机理作了简要介绍，并对其近期进展进行了评述，着重介绍了其在共聚物分子结构设计中的一些应用。

The mechanism of ATRP is introduced briefly in this paper , and the new progresses of ATRP are reviewed , emphasis on the applications of ATRP in copolymer molecular design .

通过活性正离子聚合与原子转移自由基聚合（ATRP）转换合成了β-蒎烯与甲基丙烯酸甲酯（MMA）、丙烯酸丁酯（BA）、苯乙烯（St）的新型接枝共聚物。

Graft copolymers of β - pinene with methyl methacrylate ( MMA ), butyl acrylate ( BA ) or styrene ( St ) were synthesized by the combination of living cationic polymerization and atom transfer radical polymerization ( ATRP ) .

Fe（Ⅲ）体系催化的丙烯酰胺反向原子转移自由基聚合

Reverse atom transfer radical polymerization of arylamine catalyzed by iron (ⅲ) system

N，N-二甲氨基甲基丙烯酸乙酯的原子转移自由基聚合

Study on the atom transfer radical polymerization of n , n - ( dimethylamino ) ethyl methacrylate

原子转移自由基聚合合成具有pH敏感性壳聚糖材料及其对辅酶A的控制释放

Preparation of pH-sensitive chitosan by atom transfer radical polymerization and its controlled delivery on coenzyme A

负载卤化镍（NiX2/HD）催化MMA的原子转移自由基聚合

Atom Transfer Radical Polymerization of MMA Catalyzed by Hybrid Supported Nickel Catalyst

水分散体系中由BPO或KPS引发的苯乙烯反向原子转移自由基聚合

Reverse atom transfer radical emulsion polymerization of styrene initiated by BPO or KPS

本论文采用原子转移自由基聚合制备了Poly（MethylMethacrylate）-g-polystyrene接枝共聚物和四臂星型聚苯乙烯。

In this dissertation , poly ( methyl methacrylate-co-hydroxyethyl methacrylate ) - g-polystyrene graft copolymer and star-shaped polystyrene with four arms were prepared by atom transfer radical polymerization .

原子转移自由基聚合（ATRP）在星形聚合物合成中的应用

Progress of Atom Transfer Radical Polymerization ( ATRP ) Applied to the Synthesis of Star Polymers

原子转移自由基聚合（ATRP）技术是合成结构规整性聚合物的有效途径。

Atom transfer radical polymerization ( ATRP ) is an effective route to synthesize polymers with well-defined structures .

原子转移自由基聚合（ATRP）方法是一种新发展起来的可控/活性自由基聚合方法，在合成结构可控共聚物过程中具有广泛应用。

Atom transfer radical polymerization ( ATRP ) is a new effective method to prepare controlled block copolymers .

综述了近10年来采用原子转移自由基聚合（ATRP）法合成星形聚合物的研究进展。

Star polymers synthesized by atom transfer radical polymerization ( ATRP ) in recent ten years are reviewed .

原子转移自由基聚合（ATRP）是近年来高分子合成化学中的重大进展之一。

Atom transfer radical polymerization ( ATRP ) is one of the significant developments of polymer synthesis chemistry recently .

原子转移自由基聚合（ATRP）虽然发展较晚，但是反应条件温和，单体选择范围很宽。

Atom transfer radical polymerization ( ATRP ) has been developed late , but its reaction condition is gentle .

采用过渡金属催化原子转移自由基聚合反应的方法，合成了高支化聚苯乙烯（HBPS）；

High branched PS ( HBPS ) was synthesized by means of metal-catalyzed living radical polymerization .

m-DVB和p-DVB原子转移自由基聚合动力学

Kinetic study on atom transfer radical polymerization of m-DVB and p-DVB

通过由对氯甲基苯甲酸引发的苯乙烯原子转移自由基聚合（ATRP）合成了分子量可控、分子量分布窄的新型功能聚合物。

A novel type of functional polymer with designed structure , controlled molecular weight and low polydispersities can be prepared via ATRP ( Atom Transfer Radical Polymerization ) .

这些聚合物一般是通过活性聚合方法得到的，如阴、阳离子聚合，可控开环聚合（CROP），原子转移自由基聚合（ATRP）与可逆加成-断裂链转移（RAFT）聚合。

These polymers are generally prepared by living polymerization , such as living cationic / anionic polymerization , cationic ring-opening polymerization ( CROP ), atom transfer radical polymerization ( ATRP ) and reversible addition – fragmentation transfer ( RAFT ) polymerization .

综述了普通自由基聚合和原子转移自由基聚合（ATRP）反应对壳聚糖及其衍生物进行修饰改性的研究现状。着重介绍了ATRP技术在壳聚糖接枝改性方面的应用。

The paper reviewed the modification of chitosan by free radical polymerization and atom transfer radical polymerization ( ATRP ), emphasized the application of ATRP on graft copolymerization of chitosan .

本论文从分子设计的三要素&组成、形态和功能性出发，利用原子转移自由基聚合（ATRP）和点击化学，成功合成了一系列组成不同、形态各异，且具有不同敏感性的聚合物。

Based on the composition , morphology and function , this dissertation successfully synthesized a series of stimuli-responsive macromolecules by using atom transfer radical polymerization ( ATRP ) or click chemistry .

本论文描述了两种弹性蛋白表面改性的方法：原子转移自由基聚合（ATRP）和硫代-引发转移终止剂（thio-iniferters），并对其性能进行了研究。

In this thesis , synthesis and properties of elastin graft copolymer via atom transfer radical polymerization ( ATRP ) and thio-iniferters were described .

本文由以下四个部分组成：碘原位生成物作为链转移剂的MA的DT聚合；AIBN／I2原位反应物引发St的原子转移自由基聚合（ATRP）；

The thesis consists of four parts : Degenerative transfer polymerization ( DT ) of MA with iodide in situ as a transfer agent and AIBN / I_2 / MA in situ initiated atom transfer radical polymerization ( ATRP );

概述了原子转移自由基聚合（ATRP）反应的机理、引发剂的组成、催化体系、适用单体、聚合温度、反应介质的近期研究进展；

The reaction mechanism , initiators ' composition , catalyst system , monomers suitable for use , polymerization temperature and medium of atomic transfer radical transfer polymerization ( ATRP ) are systematically summarized .

设计并通过原子转移自由基聚合方法（ATRP）合成了核壳型具有梯度极性的多羟基多臂星状聚合物刷。

Based on the atom transfer radical polymerization ( ATRP ) and the large amount of functional groups of hyperbranched polymers , core-shell multi-arm star polymer brushes with gradient polarity distribution were designed and prepared .

本文综述了螺旋聚合物的研究历程以及螺旋聚合物的合成方法，开展了原子转移自由基聚合（ATRP）制备单手性螺旋过量聚合物的研究。

The status of helical polymer and the synthesis methods are reviewed in this dissertation . The synthesis of optically active helical polymer by the atom transformation radical polymerization ( ATRP ) is carried out .

用原子转移自由基聚合（ATRP）与自缩合乙烯基聚合（SCVP）相结合合成超支化聚合物聚对氯甲基苯乙烯（PCMS），该聚合物每个分枝均以卤素原子封端。

Hyperbranched poly ( p-chloromethyl stryrene )( PCMS ) was prepared by combining atom transfer radical polymerization ( ATRP ) and self-condensing vinyl polymerization ( SCVP ) . The branches of the hyperbranched PCMS was ended with halogen atoms , which were transferred into azide groups .

由于表面引发原子转移自由基聚合（SI-ATRP）不但能够控制目标产物的形貌和性能，而且具有极强的通用性和稳定性，因此被广泛用于球型聚电解质刷的合成。

The surface-initiated atom transfer radical polymerization ( SI-ATRP ) is widely used in spherical polyelectrolyte brushes synthesis since it is not only able to control the morphology and performance of the target product , but also has a strong versatility and stability .

原子转移自由基聚合制备超支化聚合物进展

Progress in preparation of hyperbranched polymers via atom transfer radical polymerization

原子转移自由基聚合中过渡金属催化剂的研究进展

Recent advance of transition-metal catalyst system in atom transfer radical polymerization

氯代仲丁烷引发甲基丙烯酸甲酯的原子转移自由基聚合

Atom Transfer Radical Polymerization of MMA Initiated by Butyl Chloride