大分子引发剂

该共聚物可以作为大分子引发剂再引发甲基丙烯酸甲酯（MMA）进行无皂乳液聚合。

The results showed that the surfactant-free polymerization of MMA can be carried out by using saponified AMS-MAn copolymer , without any other initiator and emulsifier .

利用自由基溶液聚合技术，以过氧化苯甲酰（BPO）为引发剂，合成了大分子引发剂：苯乙烯-偏二氯乙烯（St-VDC）共聚物。

The macroinitiator ( St-VDC copolymer ) was synthesized with BPO as initiator by free radical solution polymerization technology .

聚醋酸乙烯酯和共聚物大分子引发剂引发异丁烯正离子接枝共聚合反应

The cationic polymerization of isobutylene by grafting from PVAc and its copolymer

将聚己内酯进一步和萘钾反应，得到基于己内酯的大分子引发剂；

The obtained PCL was further treated with naphthalene potassium to get a PCL-based macro-initiator .

大分子引发剂是从已商品化的功能聚合物制得或用其它活性聚合方法合成。

The macroinitiators are prepared from functional polymers available commercially or obtained by other living polymerizations .

将插入率不同的共聚物转化成大分子引发剂，通过原子转移自由基聚合合成不同接枝率的主链为聚乙烯的接枝共聚物。

The copolymers that have different incorporations were converted to macromolecular initiators , graft copolymers were synthesized by atom transfer radical polymerization ( ATRP ) .

考察各种因素对聚合反应及乳胶粒性质的影响发现：大分子引发剂对聚合反应有较大的影响。

The studies of the effects of all kinds of factors on the controllability of polymerization and the properties of emulsion showed that macroinitiators had great effects on the polymerization .

聚合反应动力学和产物分子量及分子量分布研究结果表明，大分子引发剂能够引发其它单体进行聚合反应，并且聚合为可控聚合。

The results by measuring polymerization kinetic , polymer molecular weight ( Mn ) and molecular weight distribution ( D ) show that the macro-initiator could initiate the monomers and the polymerizations are controlled .

大分子光引发剂研究进展（一）

Research Trend of Macromolecular Photoinitiators (ⅰ)

大分子偶氮引发剂法嵌段共聚物合成研究

Synthesis of Block Copolymers via Macro-Azo-initiator

简要介绍含二苯酮基的大分子光敏引发剂的合成制备、引发聚合机理及应用方面的研究进展情况。

This paper discusses , the synthesis , photoinitiation polymerization mechanism and applications of polymer photosensitized initiator containing side chain benzophenone chromophores .