动力学同位素效应

氘/氚化锆热解吸动力学同位素效应

Kinetic Isotope Effects of Desorption for Zirconium Deuteride and Tritide

氢/氘化钛热解吸的动力学同位素效应

Research on the Kinetics Isotope Effects of Titanium Hydride and Titanium Deuteride Desorbed

本文对钛氢体系中氢的热力学和动力学同位素效应进行了系统研究，其中钛氚化反应的热力学和动力学性能以及氚化钛热解析的动力学性能等在国内外鲜有报道；

Isotope effects of titanium-hydrogen system in thermodynamics and kinetics were studied . There is few report on thermodynamic and kinetic characteristics of titanium tritide reaction up to now .

天然氘核磁共振法测定环酮的烯胺化反应的一级动力学氘同位素效应

Measurement of Primary Kinetic Deuterium Isotope Effect of the Reaction of Enamine Formation Using Natural Abundance Deuterium NMR

三种合金吸氕氘表现出明显的动力学氢同位素效应。Ti&V合金吸氕氘比较，吸氕的速率快、表观反应速率常数大、表观活化能低。

In comparison to Deuterium absorption , Hydrogen absorption shows a fast reaction rate , high rate constant and low apparent active energy .

天然氘核磁共振测定一级和二级动力学氘同位素效应Ⅰ.内标的分子内与分子间竞争法

Simultaneous Measurement of Primary and Secondary Kinetic Deuterium Isotope Effects by Natural Abundance ~ 2H NMR ⅰ . Inter-as well as Intramolecular Competition using Internal Reference

应用氘核磁共振，而不用特别氘代化合物同时测定一级和二级动力学氘同位素效应。

Primary and secondary kinetic deuterium isotope effects are measured simultaneously with compounds containing deuterium in natural abundance by ~ 2H NMR according to the procedure described in the paper .

合成氨动力学方程和反同位素效应

Kinetic Equation and Reverse Isotopic Effect of Ammonia Synthesis