胶束成核

溶剂热条件下无皂乳液聚合机理遵循胶束成核和均相成核，但温度改变时自生压力影响胶粒的成核过程。

The polymerization with solvothermal method are in accordance with mechanism of homogeneous nucleation and micelle nucleation , but different pressure for different temperature posed influence on the nucleation of nanoparticles .

在考虑胶束成核和均相成核的基础上、建立了成核模型，结合建立的种子乳液共聚合模型对实验结果进行了模拟。

Based on the consideration of micell and homogeneous nucleation , nucleation model was developed . The modeling of the experimental results for unseeded emulsion copolymerization was shown by combining the nucleation model with seeded emulsion copolymerization that .

单体以乳液聚合方式聚合时，以胶束成核为主，聚合过程中生成大量聚合物微球，难于实现对颜料的有效包覆改性。

In emulsion polymerization , monomers polymerized in micelle was the mainly particle nucleation , a lot of free polymer particles were formed in the aqueous phase . It appeared that it is difficult to achieve high encapsulation efficiency by emulsion technique .