甲苯磺酰氯

通过改变6单对甲苯磺酰基β环糊精合成方法中对甲苯磺酰氯的加入方式，将反应产率由文献报道的7%，11%提高到18%，并讨论了反应条件对产率的影响；

The productivity of mono-6-O-tosyl β - cyclodextrin is promoted from 7 % , 11 % reported in previous literature to about 18 % through changing the adding mode of tosyl chloride . The effect of reaction conditions on the productivity is also concerned .

对甲苯磺酰氯的合成研究

Study Synthesis of p-Toluenesulfonyl Chloride

二乙醇胺和对甲苯磺酰氯在三乙胺存在下，反应生成N，0，O′－三（对甲苯磺酰基）双（2－羟乙基）胺，产率93%。

In the presence of triethylamine , N , O , O ' - tris ( p-toluenesulfonyl ) his ( 2-hydroxyethyl ) amine was prepared in 93 % yield by tosylation of diethanolamine with p-toluenesulfonyl chloride .

以4-甲苯磺酰氯活化的棉纤维为载体，对固定化菊粉酶的条件进行探讨。

Inulinase from Aspergillus ficuum SK004 was immobilized on cotton cloth activated with p-toluenesulfonyl chloride ( tosyl chloride ) .

同时，还改进了对甲苯磺酰氯和对甲苯磺酰甘氨酸的合成方法。

The improved methods for the syntheses of tolylsulfonyl chloride and Np-tolysulfonyl amino acids have been described in this work .

本文以硫化钠和对甲苯磺酰氯为原料，对对甲苯硫代磺酸钠的合成工艺进行了改进。

P-Toluene thio sulfonic acid sodium salt has been synthesized with sodium sulfide and p-toluenesulfonyl chloride as the raw materials .

研究了不同反应介质、操作方式、反应温度等对β-环糊精与对甲苯磺酰氯磺酰化反应的影响。

Effects of media , temperature and operation mode on the tosylation of 1 β cyclodextrin with p TsCl were studied .

研究了纤维素葡萄糖残基与对甲苯磺酰氯的摩尔比、纤维素原料（软木纤维素，棉纤维素以及蒸汽闪爆处理的软木纤维素、棉纤维素）种类及溶解方法对合成产物取代度的影响。

Moreover , effect of molar ratio of AGU / tosylchloride , cellulosic starting materials ( cotton linters , wood pulp and them treated by steam explosion ) and dissolution method of cellulose on DS_ ( Tos ) of cellulose tosylate was discussed .

采用对甲苯磺酰氯法，用聚乙二醇对青霉素酰化酶进行化学修饰，修饰酶的比活为未修饰酶的75%，稳定性比游离酶有了很大提高。

Polyethyleneglycol ( PEG ) activated by tosyl chloride was used to modify penicillin acylase ( PAC ) . The stability of the PEG PAC was much better than the free PAC . The activity of the modified enzyme was 75 % of free enzyme .