叔碳原子

对引发剂B，在温度低于180℃之前，仲碳原子最易发生接枝反应，其次是叔碳原子，当温度高于180℃后，伯碳原子、仲碳原子和叔碳原子的反应速率差不多。

For initiator B , when temperature is less than 180 ℃, MAH first reacts with secondary carbon of EB-block , secondly reacts with tertiary carbon ; when temperature is higher than 180 ℃, the reaction rate of MAH reacted primary , secondary , tertiary carbon are similar .

异丙苯通过异丙基叔碳原子上的氢原子与CaO催化剂表面碱中心发生化学吸附，弱化了异丙基叔碳原子上的C&H键，从而有利于催化异丙苯氧化合成CHP的反应。

Cumene adsorbed on the basic sites of CaO through H atom on tertiary carbon of the isopropyl group , which caused the weakening of the C-H bond on tertiary carbon of isopropyl group , and was favorable to peroxidation of cumene .

在N2气氛下的热降解过程中，CIPP中不同的碳-氯原子对CIPP的热稳定性有不同影响，叔碳-氯原子是影响CIPP热稳定性的主要因素。

The process of thermal degradation of CIPP in the N__2 atmosphere indicate that different C-Cl atoms had different effects on the thermal stability of CIPP , and the main influencing factor may be the existence of tert-carbon-chlorine atoms .