叔丁基过氧化氢

叔丁基过氧化氢（TBHP）作为常用的氧化剂，对于活化碳氢键有很大的促进作用。

Tert-butyl hydroperoxide ( TBHP ) as a common oxidant , is promoted C-H activation .

叔丁基过氧化氢选择性接近100%，过氧化氢的利用率达到836%。

The selection of tert-butyl hydroperoxide was approximate 100 % and the rate of H 2O 2 that has been used was about 83.6 % .

然后在水溶液中以十二烷基二苯醚二磺酸钠和OP-10为乳化剂，在叔丁基过氧化氢的引发作用下与其它烯类单体共聚得到含氟丙烯酸酯乳液。

The emulsion based on fluoroacrylate and other vinyl monomers was prepared via emulsion polymerization in the presence of tert-butyl hydroperoxide ( TBHF ) as water soluble initiator , sodium lauryl biphenyl ether disulfonate and OP-10 was the emulsifier .

叔丁基过氧化氢（TBHP）是重要的化工产品，广泛用作氧化剂、自由基反应的引发剂，它也是丙烯共氧化法生产环氧丙烷的常用氧源。

Tert-butyl peroxide ( TBHP ) is an important chemical products widely used as initiator of oxidant in free radical reaction , the oxidizing agent to manufacture propylene oxide from propylene .

气相色谱法测定叔丁基过氧化氢和二叔丁基过氧化物

Determination of t-Butyl Hydroperoxide and di-t-Butyl Peroxide by Gas Chromatography

以简单钙盐或镁盐为催化剂和叔丁基过氧化氢为氧化剂，不加入任何其他的碱或配体的类紫罗兰酮二烯的烯丙位氧化，迄今未见文献报道。

To date , no report involved the allylic oxidation of ionone-like dienes with the catalyst of simple calcium or magnesium salt .

在最近报道的丙二酸酯类化合物一步法合成的方法中使用的氧化剂叔丁基过氧化氢存在价格高、易爆炸等缺点，不适合工业化生产。

In the recent report about the one pot synthesis of malonic acid ester needs tert-butyl hydroperoxide exist some defect such as expensive , explosive , so it was not suit for the industrialization production .

本文研究了金属离子，特别是铈离子在叔-丁基过氧化氢分解反应中的催化性能。

Catalytic action of metal ions , especially cerium ion , in the decomposition of t-butyl hydroperoxide was investigated .

介绍了钛硅分子筛催化叔丁醇合成叔丁基过氧化氢。

The reaction of t-butanol catalyzed by HTS to prepare tert - butyl hydroperoxide was introduced .