超分子组装
- 网络supramolecular assembly
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采用超分子组装技术制备的非病毒基因传递体系,由于具有合适的纳米尺寸、可控的结构及良好的生物相容性,显示出巨大的发展潜力及应用前景。
Non-viral gene complexes fabricated by supramolecular assembly showed great potential in gene therapy due to the suitable nanometer size , controllable structure and excellent biocompatibility .
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这一工作包括有机功能分子的合成、无机半导体纳米粒子的制备、超分子组装体的形成及其高分子构筑。
This work included the synthesis of functional organic molecules , the preparation of and inorganic semiconductor nanoparticles , the formation of supramolecular assembly and its polymerization .
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十六个配合物都能与DNA发生不同强度的作用,其强弱受金属中心(种类、配位环境、配位数),配体(种类和个数),超分子组装方式等因素的影响。
All the complexes can interact with DNA , and the interactions are influenced by the metal ions ( the type , coordination environment and the coordination number ), ligands ( the type and the number ), the assembly modes and other factors .
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轮烷研究&从超分子组装到分子器件
Rotaxane : From Supramolecular Self - Organization to Molecular Devices
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基于中性芳环间电子供体-受体相互作用驱动的有机超分子组装
Supramolecular Self-Assembly Driven by Donor-Acceptor Interaction between Neutral Aromatic Subunits
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环糊精及杯芳烃超分子组装与识别的光谱研究
Spectral Study on the Molecular Assembly and Recognition of Cyclodextrins and Calixarenes
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多金属氧簇杂化反胶束在二氧化硅基质中的超分子组装及功能化
Supramolecular Assembly and Functionalization of Polyoxometalate Hybrid Reverse Micelle in Silica Matrix
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经典多金属氧酸盐超分子组装体的水热合成、结构和性质研究
Synthesis , Structures and Properties of Supramolecular Assemblies Based on Classical Polyoxometalates
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环境响应性聚合物超分子组装体的构筑和结构调控
Fabrication and Structural Tuning of Stimuli-Responsive Supramolecular Polymeric Assemblies
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取代基调控的二维超分子组装
The Modulation of Two-Dimensional Supramolecular Assemblies by Substituted Group
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超分子组装技术可以实现双亲性有机分子的有序组装,获得排列有序、层数可精确控制的分子薄膜。
Amphiphilic organic molecules can be assembled into order and layer number-controlled thin films .
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硅基介孔材料是通过有机与无机物组份间的超分子组装或协同效应而杂化形成。
Mesoporous silica materials were synthesized by using hybrid organic-inorganic composites through supramolecular assembly or cooperative effect .
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手性超分子组装研究进展
Progress in Chiral Supramolecular Assembling
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该类材料是以表面活性剂作为模板,在一定条件下模板与无机组分相互作用通过超分子组装过程形成的。
This materials are derived with supramolecular assemblies of surfactants , which template the inorganic components during synthesis .
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本文简要介绍了近二年来我们研究组在基于环糊精的纳米超分子组装方面的研究成果。
This article mainly presents our study results on the molecular assembly based on cyclodextrin in recent two years .
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人体内存在着大量的负电荷的蛋白质,可能导致基因超分子组装体的解离。
Proteins with negative charge are abundant in vivo , which probably lead to the disassembly of gene complexes .
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因此,对于卟啉-多肽结合体系的超分子组装性质成为了目前超分子化学学科的研究焦点。
As a result , the self-assemble property of porphyrin-peptide systems has formed the focus of research interests in this field .
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应用超分子组装技术将含硫和含氮的双亲性金属缓蚀剂有序单分子膜按设计方式修饰在碳钢表面。
Ordered monolayers of S-and N-containing amphipathic corrosion inhibitors were depoitod onto the surfaces of carbon steel electrode with super-molecular assembly technique .
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同时对以天然或修饰环糊精为基础的分子识别与组装,以及基于环糊精衍生物的纳米超分子组装体研究,所取得的重要成果和最新进展进行了概括与评述。
Furthermore , the new progress and important achievements for molecular recognition , self-assembly , and nano-supramolecular assembly based on nature cyclodextrin and its derivatives were summarized and reviewed . 2 .
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并考察了在溶液pH发生变化下,超分子自组装的变化。
The changes of the supramolecular self-assembly under the solution pH change .
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以荧光光谱和1HNMR谱研究了驱动四苯基卟啉锌(Ⅱ)[Zn(TPP)]咪唑基尾式卟啉铁(Ⅲ)[Fe(pImEPTPP)Cl]超分子自组装的配位键。
Coordination bonding driving supramolecular self-assembly of Zn ( TPP ) with Fe ( p - ImEPTPP ) Cl was investigated by fluorescence spectra and ~ 1H NMR .
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由细胞外基质(ECM)海藻酸钠和壳聚糖通过超分子静电组装在316L不锈钢和PET表面构建了生物相容性的多层膜,然后用戊二醛适度交联多层膜。
Second , the bio-inert multilayer membrane containing external cell matrix ( ECM ) was fabricated onto 316L stainless steel and PET via the layer-by-layer assemble of alginate and chitosan . The glutaraldehyde was employed to cross-link the multilayer membrane to improve its stability .
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1,6-二苯基-1,3,5-己三烯(1,6-diphenyl-1,3,5-hexatriene)(简称DPH)不能与α-环糊精,但可以分别与β-、γ-环糊精通过超分子自组装作用形成纳米管状结构的聚集体。
By supramolecular self assembling , 1,6 diphenyl 1,3,5 hexatriene ( DPH ) can form nanotubes with β ,γ cyclodextrins , respectively , but not with α cyclodextrin .
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规则镁铝水滑石超分子的组装及其结构分析
Supramolecular Assembly and Structural Analysis of Regular Nanocrystalline Mg-Al Hydrotalcite
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卟啉超分子的组装合成及其应用新进展
Recent progress in self-assembly and applications of supramolecular porphyrins
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超分子自组装膜修饰电极的制备及电化学应用
Preparation and Electrochemical Application of Supermolecule Self-assembled Modified Electrode
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其次,还研究了弱相互作用在超分子体系组装时的作用。
Secondly , we studied the weak interactions in the assembling of supramolecular system .
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季铵化聚4-乙烯吡啶衍生物与葫芦脲[6]的超分子自组装及性质研究
Supramolecular Self-assembly of Quaternized Poly-4-vinylpyridine Derivative with Cucurbituril [ 6 ] and Its Properties
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基于超分子自组装的分子纳米技术是一种新兴的高新技术。
Molecular nanotechnology , based on supramolecular self assembly , is emerging high technology .
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吡唑类配体在超分子自组装中的应用
Application of pyrazolyl ligands in supramolecular self-assembly