红色绿柱石

合成红色绿柱石中通道水分子构型及~1H和~（23）Na核磁共振谱表征

Channel-Water Molecular Pattern and ~ 1H , ~ ( 23 ) Na NMR Spectra Representation in Synthetic Red Beryl

结果表明，贫碱型水热法合成红色绿柱石中型和型通道水分子并存，但以型通道水分子的丰度明显占优。

The results show that type I and type II channel water molecules coexist in alkaline poor synthetic red beryl though the abundance of type I channel water molecule is distinctively dominant .

合成红色绿柱石的1HNMR谱属典型的两自旋系，分属两个独立的共振信号。

H NMR spectra , classified as the two typical spin systems , belong to two independent resonant signals respectively .

同时，1HNMR的峰形自双自旋系向单自旋系转化。证实合成红色绿柱石中通道水分子与碱金属离子之间存在明显的耦合关系。

At the same time , 1 H NMR peak shape is transformed from the bi spin system into the mono spin system , indicating a conspicuous coupling relationship between the channel water molecules and alkaline metal ions of the synthetic red beryl .