卤代芳烃

卤代芳烃的Heck和Suzuki偶联反应研究

Studies on the Heck and Suzuki Coupling Reactions of Aryl Halides

温和条件下无配体CuI催化咪唑与卤代芳烃的N-芳基化反应

Mild ligand-free CuI-catalyzed N-arylation of Imidazoles with Aryl Halides

Co（Ⅱ）配合物引发的卤代芳烃S（RN）1反应的研究

The Study on S_ ( RN ) 1 Reactions of Aryl Halides with Carbanion Induced by Co (ⅱ) Complex

本文采用过度金属Pd催化卤代芳烃与乙烯基化合物的Heck反应来合成吲哚衍生物。

We use transition metal palladium catalyses halogenated arene and vinyl compounds to compose indoline derivatives via Heck reaction in our thesis .

建立了一个卤代芳烃与磺酰胺、酰胺进行C-N偶联反应的反应体系。

A catalyst system has been developed for the N-arylation of sulfamides or amides with arly halides .

钯催化卤代芳烃Ullmann偶合反应

Palladium - Catalyzed Ullmann - Type Coupling of Aryl Halides

异化Fe（III）还原微生物在Fe（III）及金属氧化物的还原过程中可促进一些有机污染物，如芳香烃、卤代芳烃化合物、一些染料化合物及长链脂肪酸的降解。

Under Fe ( III ) or other metal oxides reduction , the dissimilatory Fe ( III ) reducers could stimulate the decomposition of some organic contaminants including aromatic compounds , halogenated aromatics , some dyes and long-chain aliphatic acids .

我们对环境友好的铜催化卤代芳烃腈化反应方法进行了改进创新：微波加热下，水溶剂中无配体Cu（OAc）2·H2O催化反应。

A practical and environmentally benign methodology for Cu-catalyzed cyanation of aryl halides was well developed with some main innovations : the use of water as the solvent and ligand-free Cu ( OAc ) 2 · H2O as the catalyst under microwave heating .

在水中使用Pd（OAc）2/DABCO催化四苯硼钠与卤代芳烃的Suzuki反应，碘代芳烃、溴代芳烃在此条件下均可顺利发生反应而生成相应的联芳基化合物，条件温和，产率较高。

Water was found a cheap and effective reaction media in Pd ( OAc ) _2 / DABCO ) catalyzed Suzuki Cross-Coupling reaction of tetraphenylboron sodium , and aryl iodides and aryl bromides were coupled smoothly to afford corresponding aryl-aryl products in water .

在上个世纪初，Ullmann发现了在计量的铜存在下，及高温（超过200oC）条件下卤代芳烃经自身偶联反应合成联芳烃化合物。

One century ago , Ullmann discovered successfully that biaryls were prepared through homocoupling reactions of aryl halides in the presence of stoichiometric copper under high temperature .

Suzuki偶联反应是合成联芳基结构最有效的方法之一，近年许多用于芳基硼酸与各种卤代芳烃偶合的催化剂相继被开发。

Suzuki cross-coupling reaction is one of the most efficient methods for the construction of Caryl-Caryl bonds . In recent years , Various efficient catalyst precursors have been developed that allow aryl iodides , bromides , and chlorides to be effectively coupled with aryl boronic acids .

由惰性卤代芳烃制备格氏试剂的新方法

A New Method to Prepare Grignard Reagent from Inert Alkyl Bromide

该模型可用于解释卤代芳烃化合物还原脱卤的机理。

The model can be used to explain the dehalogenation mechanism .

卤代芳烃生物活性的分子拓扑研究

Molecular topological research on creaturely activity for halogenated aromatic hydrocarbons

燃烧排放物中的有毒二恶英及类二恶英多氯联苯新型二恶英类卤代芳烃研究进展

Advance in new types of dioxin - like aromatic halides

二恶英类卤代芳烃的溶解度和正辛醇/水分配系数的预测

Estimation and Prediction of Solubility and Octanol-Water Partition Coefficients of Dioxin-Like Aromatic Halides

卤代芳烃的脂水分配系数与分子结构的定量关系

The Quantitative Relationship Between the Molecular Structures and the Hydrophobic Parameters of Halogenated Arenes

新型二恶英类卤代芳烃研究进展

Advance in new types of dioxin-like aromatic halides

钯催化卤代芳烃的胺化反应研究

Progress in Palladium-Catalyzed Amination of Aryl Halides

室温离子液体中CuBr-脯氨酸催化的硫醇、硫酚与卤代芳烃的偶联反应

CuBr-Catalyzed Coupling Reactions of Aryl Bromide with Thiophenol and Thiol Promoted by Proline in Ionic Liquid

应用理论线性溶解能关系预测部分卤代芳烃的正辛醇/空气分配系数

Using theoretical linear solvation energy relationships in predicting octanol / air partition coefficients of some halogenated aromatic hydrocarbons

应用分子拓扑理论预测卤代芳烃的正辛醇/水分配系数

The Prediction of the n-octyl alcohol / water partition coefficient of some halogenated arene by the molecular topological theory

镍催化卤代芳烃的电化学偶联及其机理和动力学研究含对称苯乙炔基稠环芳烃化合物的合成及化学发光研究

Electrochemical Coupling of Aromatic Halide Catalyzed by Nickel Complex , Mechanism and Kinetics ; Synthesis and Chemiluminescence Study of Symmetrically Phenylethynyl Substituted Fused Aromatic Hydrocarbons

本论文合成了一系列的杯[6]芳烃衍生物，并研究了其作为相转移催化剂用于卤代芳烃氟化反应的性能。

A series of calix [ 6 ] arene derivatives have been synthesized and their performance as PTC in the fluorination of halogenated aromatic compounds has been studied .

证实了溶剂热条件下卤代芳烃与无机氨之间胺化反应的可行性，并原位合成得到了系列含Cu/I簇配位聚合物。

We confirmed the feasibility of the amination reactions between iodobenzene and inorganic ammonia under solvothermal conditions , and synthesized a series of Cu / I cluster-based supramolecular coordination polymers .

羧甲基-β-环糊精的合成及对卤代芳烃的增溶研究芳香烃化合物的酸碱性与五种溶剂/水分配系数的相关性

Synthesis of carboxymethyl - β - cyclodextrin and its solubilization on halogenated aromatic hydrocarbons determination of acidity and basicity of aromatic compounds and their correlation with five solvent / water partition coefficients

摘要许多卤代芳烃化合物具有类似于二恶英类化合物的结构和性质，都属于持久性有机污染物，其毒性对环境和人类健康存在潜在的危害。

The structures and properties of many polyhalogenated aromatic hydrocarbons are similar with dioxin-like compounds , which have potential threatens to environment and human health as persistent organic pollutants because of their toxicity .

水解池&氧化塘系统去除卤代物与多环芳烃的初步研究

Primary study of removing halohydrocarbon and aromatics in sewage treatment system of hydrolytic Tank-Stabilization pond

卤交换法（Halex反应）采用了廉价的卤代芳烃为原料，目前已作为合成含氟芳香族化合物的主要途径。

Halogen exchange reaction use low-cost halogenated aromatic compounds as materials and it has been the mostly way to synthesize fluoro - aromatic compound .