钯催化交叉偶联反应

实验证明，以水作为反应介质可以促进钯催化交叉偶联反应的进行。

Based on the results , water as the medium can promote palladium-catalyzed cross-couplings .

无溶剂条件下钯催化交叉偶联反应研究

Palladium-Catalyzed Cross-Coupling Reactions under Solvent-Free Conditions

钯催化交叉偶联反应在化学工业、合成天然产物及生物活性物质中有着广泛的应用。

Palladium-catalyzed cross-coupling reactions have been widely applied to the chemical industry , synthesis of natural products and biological active substances .

钯催化交叉偶联反应是一类用于碳碳键形成的重要反应，在有机合成中应用十分广泛。

Palladium catalyzed cross coupling reaction which is widely used to form C C bond is an important reaction in organic synthesis .

研究结果表明胺可以作为价廉和高效的配体促进钯催化交叉偶联反应。

The results show that amine could be used as the inexpensive and highly efficient ligands to promote the palladium-catalyzed coupling reactions .

这些水相钯催化交叉偶联反应具有反应条件温和，反应产率和选择性高，反应中无需使用有毒的有机溶剂等优点。

These cross-couplings in water have several advantages , such as mild conditions , high yields and selectivity , and free of toxic solvents during the reactions .

钯催化Suzuki交叉偶联反应报道已经很多。

There are many reports on the palladium-catalyzed Suzuki cross-coupling reactions .

钯催化Stille交叉偶联反应研究新进展

Recent Progress in the Palladium-Catalyzed Stille Cross-Coupling Reactions

钯催化C-N交叉偶联反应，又称Buchwald-Hartwig反应，是实现芳胺化或胺芳化得到芳基胺化合物的的重要方法。

Pd-catalyzed cross-coupling reaction , also called Buchwald-Hartwig reaction , is an effective strategy to realize amination or arylation .

综述了钯催化Stille交叉偶联反应的最新研究进展，主要包括三个方面：（1）有机锡化合物与有机亲电试剂如卤代芳香烃、卤代烷烃、酰氯等的反应；

Recent development of the palladium-catalyzed Stille cross-coupling reactions is reviewed , which includes ( 1 ) the reactions of organotin compounds with organic electrophilic reagents such as aro-matic halides , alkyl halides , and acyl chlorides etc.

P（？）O、P（？）N螯合钯配合物催化Suzuki交叉偶联反应的研究：TFT用液晶化合物的合成

Study on the P (?) O and P (?) N Chelated Pd (ⅱ) Complexes Catalyzed Suzuki Cross-coupling Reaction : Synthesis of TFT-LCs