氢解反应
- 网络Hydrogenolysis Reaction
![氢解反应](../cache/1196318.jpg)
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由MoO3载量对KA及Kr的影响推测,对Mo/Al2O3催化剂,噻吩主要吸附于载体上,而氢解反应则发生在金属Mo上;
For Mo / Al_2O_3 catalyst , thiophene can be adsorbed on the support while hydrogenolysis of adsorbed thiophene takes place on Mo active sites .
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2-甲基戊烷在铂/担体催化剂上的异构氢解反应
The hydrogenolysis and isomerization of 2 - methyl pentane on the supported Pt-catalysts
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MECHEM是一个机器发现系统,它提出了乙烷氢解反应的一个新的化学反应机理。
MECHEM is a machine discovery system that has made a discovery in chemistry .
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也研究了反应条件对甘油氢解反应的影响。
Effect of reaction conditions was also investigated .
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螺环[2,3]己烷氢解反应机理的理论研究
A theoretical study on the mechanism of hydrogenolysis of spiro [ 2,3 ] hexane
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甘油催化氢解反应中Cu/Cr催化剂的制备方式的影响。
Five kinds of Cu / Cr catalysts were prepared by various methods and used in glycerol hydrogenolysis reaction .
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低温高活性甲酸甲酯氢解反应用新型催化剂研究
Catalysts with High Activities at Low Temperature for the Hydrogenolysis of Methyl Formate A Study on Synthesis and Use of Methyl Formate
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具有更低配位数和更高自由能的表面原子是氢解反应活性中心,溶于金属体内的氢则对氢解反应起抑制作用。
The surface atoms with low coordination , high free energy are active sites for hydrogenolysis , and hydrogen in metals inhibits the reaction .
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文章从溶剂类型、溶剂极性、溶剂对氢解反应机理和催化剂结构的失活影响等方面对甘油氢解的溶剂效应进行系统的研究。
The influencing factors of the solvents effect were studied in terms of the solvent types , solvent polarity and catalyst deactivation in the solvents .
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本论文使用的多相催化剂采用沉淀法和浸渍法制备,其主要活性成分为廉价的铜。将两种方法制备的铜基催化剂应用于甘油催化氢解反应,其活性及选择性存在差异。
In this paper , low-cost copper was used as the main active ingredient for the heterogeneous catalyst , copper-based catalysts were prepared by precipitation method and impregnation method , then applied to the catalytic hydrogenolysis reaction of glycerol .
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催化剂选择性影响因素主要是加氢裂化或氢解反应。
The selectivity of these catalysts was affected mainly by hydrocracking reaction .
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目前认为低温液相合成甲醇是由羰化和氢解组成的两步法机理,甲酸甲酯氢解是两步反应的控制步骤,氢解所用催化剂主要包括铜系催化剂和镍系催化剂。
At present , the two-step mechanism what consisted of carbonylation of methanol followed by hydrogenolysis of methyl formate was accepted .