固相合成法

综述了组合化学中的绿色固相合成技术概况，讨论了绿色化学、组合化学、固相合成法、组合化学中的聚合物载体、固相载体上的有机化学反应以及固相合成反应的分析检测方法

Combinatorial chemistry solid phase synthesis ? polymer support in combinatorial chemistry ? organic chemistry reaction on solid support and the analytical monitoring techniques in solid phase synthesis reaction

Fmoc固相合成法合成黑色素细胞刺激素（MSH）的工艺研究

Fmoc solid-phase synthesis of MSH peptide

胸腺素α1的Fmoc固相合成法

Fmoc Solid-phase Synthesis of Thymosin α 1

分别采用固相合成法和液相共沉淀法制备远红外陶瓷粉体，采用X射线小角散射法测试其颗粒分布和平均粒度，采用XRD分析其物相和SEM观察其显微结构形貌。

Liquid phase codeposition method and solid phase synthesis are adopted separately to prepare far-infrared radiating ceramic powders . Particle size distribution and average diameter are tested by small-angle X-ray scattering . Phase composition is analyzed by XRD and microstructure is observed by SEM .

方法：实验第一部分Merrifield固相合成法合成寡肽。

Methods : In the first part of the experiments , Merrifield solid phase peptide methods were applied for the peptide synthesis .

采用Fmoc固相合成法得到直链肽，通过空气氧化两个半胱氨酸的巯基生成二硫键，得到一类新型含二硫键的环肽。

A novel disulfide bond-bearing cyclopeptides has been designed and synthesized by means of air oxidation of bis ( S-Acm ) which was synthesized through Fmoc solid-phase synthesis .

结果表明：烧成温度为1160℃左右，比用传统的固相合成法烧成温度低60℃，在烧结过程中，PbO的挥发速度比用固相法小得多。

The experiments show that the sintering temperature is about 1160 ℃, which is 60 ℃ lower than that with traditional solid state methods . As a result , a very lower volatile rate of PbO was observed .

SG是只带有Asn的复杂型寡糖，相比带有6个氨基酸的SGP来说，更容易用化学法保护、修饰，保护修饰后的SG可作为底物，以固相合成法合成具有所需肽链序列的糖肽。

Compared with SGP that bears six amino acids , SG the complex-type oligosaccharide linked to a sole Asn , is easy to protect and modify chemically . The protected and / or modified SG can be a substrate for solid-phase synthesis of glycopeptides with desired sequences .

与常规固相合成法相比，水热法制备的（Na1/2Bi1/2）TiO3陶瓷样品表现出较好的压电性能，其压电性能参数d33达到了82pC/N。

Compared with ( Na_1 / 2Bi_1 / 2 ) TiO_3 ceramics made by the conventional solid state reaction method , the specimen made by the hydrothermal synthesis method had superior piezoelectric properties with its piezoelectric constant d_33 attaining a relatively high value of 82 pC / N.

比较了固相合成法与传统的液相合成法之优缺点。

The solid phase syntheses and conventional liquid organic syntheses have been compared .

结论：本固相合成法可获得高纯度特异性精子肽；

Conclusion : The high purity specific peptide was synthesized by our solid phase method .

综述了典型的固相合成法，及其在多肽、低聚核苷酸和寡糖合成中的应用。

The typical solid phase syntheses and their application in the syntheses of polypeptide , oligonucleotide and oligosaccharide have been described .

本研究分别采用固相合成法和液相共沉淀法制备远红外陶瓷粉体。

Liquid phase codeposition method and solid phase synthesis are adopted separately to prepare far-infrared radiating ceramic powders in this study .

在比较了各种合成方法后，我们采用固相合成法来制备纳米氧化锌，并对其提出了改进。

After comparing many synthesis methods , we have developed an improved method of solid state synthesis to prepare zinc oxide nanoparticles .

方法：以多肽固相合成法合成特异性精子肽，并经高效液相纯化分析及质谱分析。

Methods : The specific peptide was synthesized by a solid phase method , and then assessed by high pressure liquid chromatography and mass spectrometric analysis .

采用不同的合成方法（高温固相合成法、溶胶凝胶法、燃烧合成法等）制备了高温质子导体。

In this paper , the high temperature proton conductor was prepared by various synthetic methods such as high temperature solid-state reaction , sol-gel and combustion .

用于合成陶瓷粉体的方法有多种，如：固相合成法、沉淀法、溶胶凝胶法、水热法等。

Many methods are applied for preparing the ceramic powders , such as solid state reaction , precipitation , sol-gel and hydrothermal method and so on .

本文介绍了钴及其化合物一维纳米材料，如纳米线、纳米棒和纳米管的制备方法及其最新研究进展，包括热分解法、模板法、分子自组装、固相合成法和化学溶液法等。

Progress in preparation method of cobalt and cobalt compound , in recent years including thermal decomposition method , template method , self-assembling , solid-state method and Chemical solution method is presented and commented in detail .

采用普通固相合成法和铌铁矿前驱体法合成了CaO-MgO-Nb2O5-TiO2微波陶瓷粉体，讨论了这两种粉体制备方法对CaO-MgO-Nb2O5-TiO2微波陶瓷微观结构和介电性能的影响。

The powders of CaO-MgO-Nb_2O_5-TiO_2 ceramic were prepared by two methods , solid reaction method and precursor method . The effect of the two synthesis methods on microstructure and dielectric properties of CaO-MgO-Nb_2O_5-TiO_2ceramics were discussed in this paper .

综述了LiMnO2的几种主要制备方法，并着重介绍了高温固相合成法、乳化法、水热合成法及离子交换法近年来的研究进展。

The main preparation methods for LiMnO_2 were reviewed . A particular introduction was made on the development in the researches of high-temperature solid-state synthesis process , emulsion process , hydrothermal synthesis process and ion exchange process in recent years .

采用固相合成法，在400℃合成了掺氟质量分数分别为0.059%、0.19%、0.35%和0.56%的系列修饰锂钒氧化物。结果表明，掺氟降低了锂钒氧化物中钒的平均价态。

Via the solid-phase synthesizing method , a series of fluorine ion doped lithium vanadium oxides with the fluorine contents of 0.059 % , 0.19 % , 0.35 % and 0.56 % ( mass fraction ) was synthesized at 400 ℃,( respectively ) .

与常规固相合成法相比，柠檬酸盐法合成的La0.6Sr0.4Co0.8Fe0.2O3具有更高的烧结活性和电导率。

Compared with the La_ ( 0.6 ) Sr_ ( 0.4 ) Co_ ( 0.8 ) Fe_ ( 0.2 ) O_3 synthesized by the conventional solid state reaction method , samples synthesized by the citrate method exhibits better sintering activity and electrical conductivities .

无机新材料都是通过一定技术和方法制备出来的。主要合成方法有：固相合成法和液相沉淀法等。液相沉淀法是将原料配成溶液后进行化学变化，合成无机新材料。

New type inorganic materials are prepared by technique and certain methods which include solid-phase reaction and liquid precipitation etc. In liquid phase conditions it is the most common way to synthesize new type inorganic materials using liquid precipitation which uses the substance dissolving in water to produce insoluble substance .

方法：固相多肽合成法合成NC及其片段；

METHODS : Peptides were synthesized by solid phase peptide synthesis .

轻稀土氟化物的微波固相快速合成法

Rapid Synthesis of Light Rare Earth Fluorides in a Microwave Field

方法采用固相多肽合成法，使用逐步缩合的战略合成奥曲肽。

Method Octreotide was synthesized by the solid-phase peptide synthesis method and stepwise condensation strategy .

结果表明：该法在合成温度、煅烧时间、粒度大小及分布等方面均优于传统的高温固相反应合成法。

It proved that this method had many advantages over the traditional high temperature solid state reaction method on such aspects as the synthetic temperature , calcination duration and particle size and its homogeneity , etc.

纳米氟化铈（Ⅲ）的微波固相氧化还原合成法

Synthesis of Nanostructure Cerium (ⅲ) Fluoride by Oxidation - Reduction Reaction in Microwave Radiation Field

在已有的文献报道中，一般使用固相合成，通过灼烧法，Czochralski提拉法或固相晶体生长法来合成钼酸稀土钠盐晶体；

In the reported literatures , always used solid-stated synthesis methods to produce NaLn ( MoO4 ) 2 crystal through cauterant method , Czochralski technique or solid-state crystal growth method .