亲电性
- Electrophilicity;eletrophilicity
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环境污染物多数为亲电性(Electrophile)化学物质,如TCDD,CdCl2,多氯联苯,HgCl2,Pb(C2H3O2)2等。
Most of environmental pollutants are electrophile chemicals , such as TCDD , CdCl_2 , HgCl_2 , Pb ( C_2H_3O_2 ) _2 and so on .
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亲电性化学物是环境中的主要污染物,所以越来越引起环境科学研究者的高度关注。
Electrophile chemical is the major pollutant in the environment , this is very concerned by many of environmental scientists .
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从电性角度讨论了有机物分子的亲电性和亲核性问题,并阐述了两者在有机合成中的应用。
In this paper , electroaffinity and nucleophilicity of organic compound have been investigated , and their application in organic synthesis also has been discussed .
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重氮乙酸乙酯的碳原子既具有亲电性又具有亲核性,而且是一个偶极离子,所以它的反应是多种多样的。
The carbon atom of ethyl diazoacetate is not only electrophilic and nucleophilic , but also is a dipolar ion , so the reaction about it is varied .
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推测在两类催化体系中,氧化剂均在具有特定结构和价态的铁或铜活性位上活化,产生导致丙烯环氧化反应发生的亲电性活性氧物种。
We propose that the oxidant is activated on active iron or copper sites with peculiar structures and oxidation states , forming active oxygen species responsible for the epoxidation of propylene .
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并且对亲核试剂的体积效应、溶剂效应对亲核性影响,底物上吸电子基团的数目、吸电子能力对亲电性的影响,以及亲核取代反应的发生部位受哪些因素影响进行探讨。
At the same time , discuss about the impact factor to nucleophilicity such as the number of attract electron group 、 ability of attract electron and the nucleophilic substitution reaction part .