三氯硅烷

三氯硅烷的制备及精制工艺进展

Progress on preparation and purification of trichlorosilane

工业上，三乙氧基硅烷由三氯硅烷醇解法制得，该反应工艺复杂，收率低，反应过程中伴有大量的氯化氢气体产生，腐蚀设备，污染环境。

Triethoxysilane is prepared by alcoholysis of trichlorosilane in industry , the process of which is complex , associated with a large number of hydrogen chloride gases , apparatus corrosion , pollution of the environment and low-yield .

固载AlCl3催化甲基三氯硅烷/三甲基氯硅烷再分配反应实验研究

Study on Redistribution of Methyltrichlorosilane and Trimethylchlorosilane over AlCl_3 Supported Catalyst

AlCl3/活性炭催化甲基三氯硅烷与低沸物再分配反应研究

Study on Redistribution of Methyltrichlorosilane and Low-boiling Residues Using Activated Carbon Supported AlCl_3 Catalysts

本文研究SiC的生产工艺是气相沉积法（CVD），生产原料是甲基三氯硅烷和氢气（MTS／H2）。

The manufacturing technique of SiC in this article is Chemical Vapor Deposition ( CVD ) and the producing plant is methyltrichlorosilane and hydrogen ( MTS / H2 ) .

以乙二胺和甲基三氯硅烷为主要原料，通过逐步偶联聚合制备了梯形聚硅氧烷（PMSQ）；

Hydroxy-terminated ladder-like polysiloxane was synthesized from ethylene diamine and monomethyltrichlorosilane by stepwise coupling polymerization .

甲基二氯硅烷+甲基三氯硅烷+二甲基二氯硅烷+苯多元系常压汽液平衡研究

Isobaric Vapor-Liquid Equilibrium for Methyldichlorosilane + Methyltrichlorosilane + Dimethyldichlorosilane + Benzene Systems

甲基三氯硅烷水解反应机理的密度泛函研究

Density functional theory study on the mechanism of hydrolysis reaction for methyltrichlorosilane

三氯硅烷储罐区火灾爆炸事故分析与控制

Analysis and Control of Fire and Explosion Accident on a SiHCl_3 Tank Area

十八烷基三氯硅烷表面改性钛酸钾晶须

Surface Modification of Potassium Titanate Whiskers with n-octadecyltrichlorosilane

本文分别对甲基三氯硅烷有机铝法转化反应和歧化反应及其组合工艺进行了研究。

The methylation and redistribution reactions of methyltrichlorosilane and their integration technology are investigated .

结果表明，此保护剂存在下的铂胶体对乙炔和三氯硅烷的硅氢加成反应有良好的反应活性和稳定性。

Results showed that the colloidal platinum was stable and active for the hydrosilylation .

本文进一步选用搅拌床反应器进行甲基三氯硅烷有机铝法转化反应。

It is found that methyltrichlorosilane is more reactive in an agitated bed reactor .

由甲基三氯硅烷醇解副产物生产3~＃防水剂

The preparation of 3 ￣ # Water proofing Agent from the Alcoholysis Coproduct of Methyltrichlorosilane

介绍了由甲基三氯硅烷与甲醇进行酯化反应制备一种硅烷偶联剂甲基三甲氧基硅烷的方法。

Methyltrimethoxylsilane-a silane coupling agent was prepared by the esterification reaction of Methylerichlorosilane and Meghyl alcohol .

甲基三氯硅烷的氯化方法

Process for the chlorination of methyltrichlorosilane

甲基三氯硅烷歧化法制备二甲基二氯硅烷

Preparation of Dimethyldichlorosilane Disproportionated from Methyltrichlorosilane

本论文旨在综合利用多晶硅产业的副产物四氯化硅SiC14，采用格氏法工艺，研究合成苯基三氯硅烷。

This thesis aims at the comprehensive utilization of polysilicon industry by-products , using grignard technology to synthesize phenyl trimethoxysilane silane .

本文利用苯基三氯硅烷和硅胶表面羟基反应制备了苯基化硅胶。

The phenylated silica gel has been prepared by the reaction between the surface hydroxyl groups of silica gel and phenyl trichlorosilane .

首先采用固定床反应器对甲基三氯硅烷有机铝法转化反应进行了研究，发现反应温度、反应压力、进料配比、催化体系等因素对反应有较大影响。

The methylation reactions of methyltrichlorosilane can be occurred with methyl chloride in a fixed bed reactor in the presence of aluminum , which serves as a halogen acceptor .

其主要工艺流程是：首先合成苯基氯化镁，再以苯基氯化镁和四氯化硅为原料合成苯基三氯硅烷。

The technological process is as follows : First , synthesize phenyl magnesium chloride . Second , phenyl trimethoxysilane silane is synthesized by Grignard method with phenyl magnesium chloride and four chlorinated silicon as raw material .

当氯甲烷与甲基三氯硅烷的量之比为1∶1～04∶1时，甲基三氯硅烷的转化率为416%～432%，二甲基二氯硅烷的收率为842%～850%。

When the ratio of methylchloride to methyltrichlorosilane were 1:1 ~ 0 4:1 , the transform ratios of methyltrichlorosilane were 41 6 % ~ 43 2 % and the yields of dimethyldichlorosilane were 84 2 % ~ 85 % .

为了控制氧化钙水化反应急剧，并大量放热而引起各种危害，本文中用十八烷基三氯硅烷偶联剂在室温对氧化钙粉体进行疏水化表面改性。

For controlling the intensive hydrate reaction and the great heat released in the process and reducing the harm that caused by CaO , the hydrophobic surface-modification of CaO particles by silane cou - pling agent-octadecyl trichlorosilane at room temperature was intro - duced .

文中论述了苯基氯硅烷的清洁生产工艺，提出了用格氏法合成苯基三氯硅烷的研发思路，从根本上解决传统方法能耗高、副产物多，环境污染的缺点。

The thesis discusses the phenyl chlorine silane cleaner production technologies , and puts forward the synthesis of phenyl trichlorosilane technical route through the application Grignard reaction which can solve shortcomings of traditional methods , that is high energy consumption , more by-products , and environment pollution . 2 .

以氯化亚铜为催化剂，三乙胺为缚酸剂，丙酮与乙烯基三氯硅烷为原料反应制取乙烯基三异丙烯氧基硅烷。

Vinyltriisopropenyloxysilane was prepared with cuprous chloride as catalyzer , triethylamine as absorb acid agent , acetone and vinyltrichlorosilane as raw materials .