质子转移反应
- 网络proton transfer reaction
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用热分析方法筛选出了GAP/AN推进剂有效的燃速调节剂MO,它能促进硝酸铵热分解过程中质子转移反应,因而使GAP/AN推进剂燃速提高。
MO can increase the burning rate of GAP / AN propellant due to promoting the proton transfer reaction of AN decomposition . The burning rate modifier MO is an effective material to increase the burning rate and decrease burning rate pressure exponent of GAP / AN propellant .
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氨和甲醇团簇中的质子转移反应
The Proton Transfer Reaction in the Binary Cluster of Ammonia and Methanol
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本文用质量分析离子动能谱/碰撞诱导解离谱和动能释放等方法研究了由甲醇质子转移反应以及CH3~+和H2O缔合反应生成的CH5O~+离子。
CH_5O ~ + ions produced by proton-transfer reaction on CH_3OH as well as association reaction between CH_3 ~ + and H_2O are studied by means of MIKES / CID and kinetic energy release .
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尿酸质子转移反应的理论研究I&分子内质子转移研究
The theoretical study of the intramolecular proton transfer of uric acid molecule
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水杨酸激发态质子转移反应及其溶剂效应的理论研究
A Theoretical Study of Excited-State Proton Transfer Reaction of Salicylic Acid and Its Solvent Effect
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气相质子转移反应中热化学和动力学的关系
The Correlation between Thermochemistry and Kinetics in the Proton Transfer Reactions of Small Proton Bound Clusters
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辉光放电离子源质子转移反应质谱对水中苯的分析方法研究
Study on detection of benzene in water using proton transfer reaction mass spectrometry with a glow discharge ion source
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由于在聚合过程中存在质子转移反应,引发剂与单体的摩尔比会影响所得聚合物的结构。
The amount of initiator used in the polymerization could affect the structure of polymer based on a proton-transfer process .
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2-(2′-羟基苯基)苯并咪唑的质子转移反应和光谱性质的理论研究
A Theoretical Study of Proton Transfer Reaction and Spectroscopic Properties of 2 - ( 2 ' - Hydroxyphenyl ) benzoimidazoIe
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苯甲酰苯胺激发态质子转移反应的理论研究Ⅰ.酰胺、亚胺酸的顺、反异构和二聚
A Theoretical Study of Proton-Transfer Reaction of Benzanilide ⅰ . The cis , trans Tautomerization and Dimerization of Amide and Imidic Acid
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此外,扩环修饰导致碱基间双质子转移反应的活化能和反应热降低。
In addition , the hetero-ring expansion can lower the activation barriers and reduce the reaction heats of the inter-base double proton transfers .
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对甲醇/水混合团簇的多光子电离质谱研究得出,电离产物均为质子化的团簇离子,分析结果表明其产生机理是团簇内发生了质子转移反应。
The studies of MPI-MS ( methanol and water ) indicated , the products of ionization were protonated cluster ions , which were produced from the proton transfer reactions in the binary clusters .
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而涉及质子转移的反应途径则是一个新的发现;
The one dealing with proton transfer shows a new feature of the titled compound 's thermal decomposition .
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然而,由于反应体系的复杂性,目前对质子转移在反应过程中的可能机理也仅局限于猜测,或是对质子转移的深入研究没有能够很好地解释实际的反应机理。
However , because of the complexity of the reaction systems , the researches about the possible mechanism of proton transfer is only hypothesized but not demonstrated , or the deep researches of proton transfer have not been combined to explain the mechanism of the practical reactions .
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可膨胀石墨作为多相催化剂,可用于催化合成具有质子转移的有机反应。
As a kind of polyphase catalyst , expandable graphite could be used in organic reaction which had proton transfer .
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质子转移在许多化学反应和生物过程中起很重要的作用。
Proton transfer plays an important role in many chemical reactions and biological processes .
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2-(2′-羟基-5′-甲基苯基)苯并三氮唑质子转移的光谱和反应机理
The Spectroscopy and Mechanism of Reaction on Proton Transfer in 2 - ( 2 ' - Hydroxy-5 ' - Methylphenyl ) Benzotriazole
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大量的理论和实验研究丰富了关于质子转移在可能的反应机理、引发异构现象以及其它一些性质方面的认识。
Many theoretical and experimental researches have enabled us to understand the role that proton transfer play in the possible reaction mechanisms and in the induced isomerization processes .
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配体作为质子运输工具参与反应,协助质子转移,进而降低反应的活化能和改变反应的路径。
The ligands , as a proton shuttle , can take part in the reaction and assist the transfer of proton , and further lower the reaction energy barriers and change the reaction routes .