质子转移反应

  • 网络proton transfer reaction
质子转移反应质子转移反应
  1. 用热分析方法筛选出了GAP/AN推进剂有效的燃速调节剂MO,它能促进硝酸铵热分解过程中质子转移反应,因而使GAP/AN推进剂燃速提高。

    MO can increase the burning rate of GAP / AN propellant due to promoting the proton transfer reaction of AN decomposition . The burning rate modifier MO is an effective material to increase the burning rate and decrease burning rate pressure exponent of GAP / AN propellant .

  2. 氨和甲醇团簇中的质子转移反应

    The Proton Transfer Reaction in the Binary Cluster of Ammonia and Methanol

  3. 本文用质量分析离子动能谱/碰撞诱导解离谱和动能释放等方法研究了由甲醇质子转移反应以及CH3~+和H2O缔合反应生成的CH5O~+离子。

    CH_5O ~ + ions produced by proton-transfer reaction on CH_3OH as well as association reaction between CH_3 ~ + and H_2O are studied by means of MIKES / CID and kinetic energy release .

  4. 尿酸质子转移反应的理论研究I&分子内质子转移研究

    The theoretical study of the intramolecular proton transfer of uric acid molecule

  5. 水杨酸激发态质子转移反应及其溶剂效应的理论研究

    A Theoretical Study of Excited-State Proton Transfer Reaction of Salicylic Acid and Its Solvent Effect

  6. 气相质子转移反应中热化学和动力学的关系

    The Correlation between Thermochemistry and Kinetics in the Proton Transfer Reactions of Small Proton Bound Clusters

  7. 辉光放电离子源质子转移反应质谱对水中苯的分析方法研究

    Study on detection of benzene in water using proton transfer reaction mass spectrometry with a glow discharge ion source

  8. 由于在聚合过程中存在质子转移反应,引发剂与单体的摩尔比会影响所得聚合物的结构。

    The amount of initiator used in the polymerization could affect the structure of polymer based on a proton-transfer process .

  9. 2-(2′-羟基苯基)苯并咪唑的质子转移反应和光谱性质的理论研究

    A Theoretical Study of Proton Transfer Reaction and Spectroscopic Properties of 2 - ( 2 ' - Hydroxyphenyl ) benzoimidazoIe

  10. 苯甲酰苯胺激发态质子转移反应的理论研究Ⅰ.酰胺、亚胺酸的顺、反异构和二聚

    A Theoretical Study of Proton-Transfer Reaction of Benzanilide ⅰ . The cis , trans Tautomerization and Dimerization of Amide and Imidic Acid

  11. 此外,扩环修饰导致碱基间双质子转移反应的活化能和反应热降低。

    In addition , the hetero-ring expansion can lower the activation barriers and reduce the reaction heats of the inter-base double proton transfers .

  12. 对甲醇/水混合团簇的多光子电离质谱研究得出,电离产物均为质子化的团簇离子,分析结果表明其产生机理是团簇内发生了质子转移反应。

    The studies of MPI-MS ( methanol and water ) indicated , the products of ionization were protonated cluster ions , which were produced from the proton transfer reactions in the binary clusters .

  13. 而涉及质子转移的反应途径则是一个新的发现;

    The one dealing with proton transfer shows a new feature of the titled compound 's thermal decomposition .

  14. 然而,由于反应体系的复杂性,目前对质子转移在反应过程中的可能机理也仅局限于猜测,或是对质子转移的深入研究没有能够很好地解释实际的反应机理。

    However , because of the complexity of the reaction systems , the researches about the possible mechanism of proton transfer is only hypothesized but not demonstrated , or the deep researches of proton transfer have not been combined to explain the mechanism of the practical reactions .

  15. 可膨胀石墨作为多相催化剂,可用于催化合成具有质子转移的有机反应。

    As a kind of polyphase catalyst , expandable graphite could be used in organic reaction which had proton transfer .

  16. 质子转移在许多化学反应和生物过程中起很重要的作用。

    Proton transfer plays an important role in many chemical reactions and biological processes .

  17. 2-(2′-羟基-5′-甲基苯基)苯并三氮唑质子转移的光谱和反应机理

    The Spectroscopy and Mechanism of Reaction on Proton Transfer in 2 - ( 2 ' - Hydroxy-5 ' - Methylphenyl ) Benzotriazole

  18. 大量的理论和实验研究丰富了关于质子转移在可能的反应机理、引发异构现象以及其它一些性质方面的认识。

    Many theoretical and experimental researches have enabled us to understand the role that proton transfer play in the possible reaction mechanisms and in the induced isomerization processes .

  19. 配体作为质子运输工具参与反应,协助质子转移,进而降低反应的活化能和改变反应的路径。

    The ligands , as a proton shuttle , can take part in the reaction and assist the transfer of proton , and further lower the reaction energy barriers and change the reaction routes .