茂金属

SBS加氢茂金属催化剂开发动向

New developing trends of metallocene catalysts for SBS hydrogenation

茂金属/烷基铝/B（C6F5）3催化体系催化乙烯聚合

Ethylene polymerization catalyzed by metallocene / AlR_3 / B ( C_6F_5 ) _3

第ⅣB族非茂金属烯烃聚合催化剂研究进展

Advances in non-metallocene ⅳ B group metal catalysts for olefin polymerization

C1桥联的茂金属化合物（Cp）CR1R2（Flu）MCl2的合成及其催化烯烃聚合活性

Synthesis of C_1 Bridge-containing Metallocene Catalysts and Their Catalytic Activities for Olefin Polymerization

茂金属化合物对苯乙烯丁二烯嵌段共聚物SBS催化加氢的研究

A Study of Catalytic Hydrogenation of Copolymer of PS-PB-PS ( SBS ) with Titanocenes

概述了国外SBS、SIS等聚合物加氢茂金属催化剂的研究开发进展；

The article resumes world 's research advance on metallocene catalysts for SBS hydrogenation ;

用茂金属聚乙烯弹性体（mPE）代替传统的弹性体，对PP的增韧改性进行了研究。

MPE was used to replace the conventional elastomers in the toughening modification of PP.

负载型非茂金属催化剂聚合制备UHMWPE

Preparation of UHMWPE by Supported Non-metallocene Catalysts

以茂金属弹性体为增韧树脂，对聚丙烯（PP）进行共混增韧改性，用下吹水冷方法生产PP薄膜。

With metallocene elastomer as toughening resin , Polypropylene is modified in blending toughening and produced into blown film by water-cooled downward extrusion method .

茂金属催化剂在LLDPE装置上的应用

Application of metallocene catalyst in LLDPE plant

茂金属SiO2的载体化研究（Ⅲ）&茂金属载体催化剂用于乙烯均聚

Study of SiO_2 supporting on metallocene (ⅲ) & study of ethylene polymerization via metallocenes supported with SiO_2

不对称茂金属[Me2C（Cp）（Ind）]ZrCl2催化剂制备支化聚乙烯的研究

Branched Polyethylene Prepared by Asymmetric Metallocene [ Me_2C ( Cp )( Ind ) ] ZrCl_2

茂金属聚乙烯（mPE）/高压聚乙烯（LDPE）共混熔体的流变学

Rheological Behavior of Metallocene PE / LDPE Blend

茂金属PP以其独特的性能，在纤维级专用树脂市场具有广阔的应用前景。

PP synthesized with metallocene catalyst possesses unique properties , and thereby exhibiting a broad application prospect in the market of fiber grade PP speciality resins .

利用SEM、力学性能测试等分析方法，研究了茂金属聚乙烯（mPE）接枝丙烯酸缩水甘油酯（GMA）所得接枝物增韧PET的形态结构与性能的关系。

Morphology and mechanical properties of PET toughened by mPE g GMA were studied by means of SEM and mechanical property test .

详细叙述了采用茂金属催化剂生产的聚烯烃，如聚乙烯（PE）、聚丙烯（PP）的性能及应用情况。

The article also examines the applications and performance of some olefin polymers produced using metallocene catalysts , such as polyethylene ( PE ) and polypropylene ( PP ) .

RESS共沉析制备负载型茂金属催化剂（Cp2TiCl2/PMMA）微粒

Study on Producing Microparticles of Supported Metallocene Catalyst ( Cp_2TiCl_2 / PMMA ) by Co-Precipitation of RESS

概述了采用茂金属催化剂生产的sPS（间规聚苯乙烯）的各种优异性能及其应用领域，并作了市场预测。

The excellent properties and applications of sPS by metallocene catalyst were introduced , and the market of sPS were analyzed .

茂金属乙烯/苯乙烯假无规共聚物（ESI）的研究进展

Research advancement of metallocene ethylene-styrene interpolymer

茂金属SiO2的载体化研究（Ⅰ）&rac-Et（Ind）2ZrCl2在SiO2上的负载方式

Study of supporting metallocene on SiO_2 ( I ) & supporting model of Et ( Ind ) _2ZrCl_2 on SiO_2

茂金属催化体系因其具有超高活性和单一活性中心，催化α-烯烃聚合所得的产物拥有梳状结构，各项性能非常优异，是a-烯烃聚合制备超高粘度PAO的理想催化剂。

Metallocene catalytic system is an ideal catalyst for alpha-olefin polymerization because of their extra high activity and single active center .

采用刚性无机填料对茂金属聚乙烯（mPE）弹性体增韧聚丙烯（PP）二元共混体系进行增强，从而制得PP/mPE/无机填料三元复合材料。

Rigid inorganic fillers were used to reinforce PP / mPE binary blends , thus PP / mPE / filler ternary composites were prepared .

由于茂金属催化剂价格昂贵，国内生产的聚丙烯多为Ziegler-Natta等规聚丙烯。

The metallocene catalyst is expensive , so most polypropylene in domestic industry is prepared by Ziegler-Natta catalyst .

烯烃聚合催化剂主要包括Ziegler-Natta催化剂、茂金属催化剂和茂后过渡金属催化剂。

The field of olefin polymerization catalysis has experienced Ziegler-Natta catalysts , metallocene catalysts and post-metallocene catalysts periods .

采用相转移法合成了含有烯丙基的环戊二烯基配体，并利用这种配体合成了茂金属化合物MC。

The allyl substituted cyclopentadienyl ligand was synthesized in the method of phase transfer , then the metallocene compound MC was accordingly synthesized on the basis of the ligand .

以复合茂金属催化剂和双载体茂金属催化剂催化乙烯聚合、考察聚乙烯（PE）分子量分布变化情况。

The composite metallocene catalyst and metallocene catalyst supported on mixed carrier was employed for ethylene polymerization , respectively . The variation in molecular weight distribution ( MWD ) of polyethylene ( PE ) was studied .

聚苯弹性体（PSE）是一类新型的茂金属聚合物，通常苯乙烯含量可达80wt%。

Polystyrene elastomers ( PSE ) are a series of novel metallocene polymers , typically containing up to about 80wt % styrene .

研究了茂金属催化乙烯丁烯1共聚物mPE和LDPE共混物的流变行为。

The rheological behavior was studied for blends of metallocene catalyzed ethylene / 1-butene copolymer ( mPE ) and low density polyethylene ( LDPE ) .

概述了茂金属催化剂和单活性中心技术的发展，介绍了聚乙烯（PE）生产技术新的发展动向，如双峰PE生产技术、反应器新配置技术、冷凝态和超冷凝态技术。

This paper summarized the development of metallocene catalyst and single-site center technology , and introduced the developing trends of polyethylene producing processes including bimodal PE production technology , responser new disposition technology and condensed and super-condensed technology .

用茂金属催化剂制得间规聚苯乙烯（sPS）是一类新型结晶聚合物，具有优良的耐热性、耐化学性和电气性能。

Syndiotactic polystyrene ( sPS ) produced with metallocene catalyst is a novel crystalline polymer that possesses excellent electronic / electric properties and good abilities to resist heat and chemicals .