硫酚
- 网络thiophenol;thiophenols;ArSH;PATP
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含分子内氢键的苯硫酚在水相中的Michael加成反应
Michael Addition Reaction of Thiophenol with Intramolecular Hydrogen Bond in Aqueous Medium
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从金纳米粒子粒径的选择、在金溶胶中加入苯硫酚的量及反应时间、抗体对标记金溶胶标记分子的SERS信号的影响进行了研究。
This paper studied factors affecting FT-SERS reporter-labeled immunogold colloids such as the sizes of gold particles , the amount of thiophenol in gold colloids and processing time , and whether goat anti-rat antibody would influence the SERS of reporter-labeled gold colloids .
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例如,对-甲苯硫酚作添加剂时,使相对量子收率φO2/φN2增加到1.8。
For example P-toluene thiol as additive increases the relative quantum yield φ O2 / φ N2 to 1.8 .
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用二甲苯作溶剂来代替1,2,4-三氯苯使五硫化二磷和硫酚反应,制得的Japanese试剂产率由58%提高到72%
Phosphorus pentasulfide reacted with thiophenol in xylene instead of 1,2,4 trichlorobenzene to give Japanese reagent , the yield increased from 58 % to 72 % .
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芳香族硝基化合物与苯硫酚钠盐的亲核取代反应&自由基IPSO取代机理
Studies on the Reaction of Aromatic Nitro Compounds with Sodium Phenylthiolate & Radical IPSO Substitution Mechanism
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从苯并噻唑开始,制备了2异丙氨基苯硫酚,并把它作为定时基团,合成了2种DIAR成色剂。在中间体的合成中,用固体光气代替光气得到了理想结果。
Two DIAR couplers were synthesized with 2 ( isopropylamino ) benzenethiol as timing group , which was synthesized from benzothiazole and triphosgene used as a substitute of phosgene , and good result was obtained .
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紫外光谱法测定汽油中硫酚类及苯酚类化合物
The Determination of Thiophenols and Phenols in Gasoline by Ultra Violet-Spectrophotometry
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β-氟烷基烯基碘与硫酚负离子的反应
The Reactions of β - fluoroalkyl Vinyl Iodides with Aryl Thiolate Ions
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此外,并且对该方法的容忍能力进行研究,发现该方法同样可以很好的应用于苯硫酚与烷基胺类化合物。
Moreover , this procedure affords good tolerates to alkylamine and thiophenol .
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手性β-羟基胺在苯硫酚与查耳酮加成反应中的不对称催化作用
Asymmetric Addition of Thiophenol to Chalcone Catalyzed by Chiral β - Hydroxy Amines
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苯硫酚及其衍生物在银电极表面的吸附取向
Adsorption Orientation of Thiophenol and Its Derivatives on the Surface of Silver Electrodes
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橡胶塑解剂五氯硫酚中硫含量的测定
Determination of Sulfur Content in The Rubber Peptizer Pentachlorothiophenol
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苯硫酚对固氮酶催化活性的影响
The Effects of Thiophenol on Catalytic Activities of Nitrogenase
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微电解催化氧化A/O法处理苯硫酚废水
Thiophenol wastewater treatment by microelectrolysis-catalytic oxidation-A / O
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得到了均聚芳香硫酚环状低聚物的相对分子质量及其分布信息;
The relative molecular mass and distributions of de - gree of polymerization were obtained .
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室温离子液体中CuBr-脯氨酸催化的硫醇、硫酚与卤代芳烃的偶联反应
CuBr-Catalyzed Coupling Reactions of Aryl Bromide with Thiophenol and Thiol Promoted by Proline in Ionic Liquid
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五氯硫酚的毒性研究
Studies on toxicity of pentachlorothiophenol
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反应中,除生成笨硫酚等取代产物外,还生成还原产物苯。
In this reaction , besides substitution products thiophenol etc , the reduction product benzene is formed .
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在第二章,我们还研究了硫酚、羟基/巯基杂环芳烃与缺电子卤代苯的偶联反应。
In this chapter , we also studied the coupling of thiophenol with electron-deficient aryl halides through SnAr reaction .
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用电聚合的方法在金电极上制备了以对硫磷为模板分子的自组装邻氨基硫酚分子印迹膜传感器。
A novel electrochemical sensor for the detection of parathion based on molecularly imprinted polymer of self-assembled o-aminothiophenol onto gold electrode was constructed .
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综述了近年来1,1′-联二萘2,2′-二硫酚的制备、拆分及在不对称合成中的应用研究进展,引用文献23篇。
The preparation , resolution and application in dissymmetrical synthesis of 1,1 ′ - binaphthalene-2,2 ′ - dithiol have been reviewed with 23 references .
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本文提出用硫酸镁沉淀分离&硫氰酸盐萃取光度法测定铌钽中的微量钨,避免使用异臭的二硫酚试剂。
A method has been developed for the determination of micro amounts of tungsten in Nb and Ta by thiocyanate after separation with magnesium sulphate .
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方法:以取代苯硫酚为原料,经多步反应制得目标化合物,并采用琼脂2倍浓度稀释法测定目标化合物的抗真菌活性。
Methods : Substituted thiophenols were used as starting material , the target compound was synthesized through several steps and their in vitro antifungal activity was studied .
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苯硫酚采用倾斜的方式吸附,使得苯环与基底间表现一定程度的相互作用;吸附的对巯基苯胺则因质子化氨基间的静电相互作用而完全垂直于电极表面;
The ring of thiophenol is tilted to the normal of the electrode surface , leading to certain extent of interaction between the benzene ring and the electrode surface .
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五氯硫酚锌盐的一些基本的危险性参数,如燃烧爆炸性能,目前国内外报道极少。
Some basic danger parameters about zinc salt of pentachlorothiophenol ( ZSPP ), such as the property of combustion and explosion were seldom available from domestic and overseas literatures .
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我们选用1,4-苯二硫酚有机分子来构造分子结,设金属电极由金来构成。
In our calculations , an organic molecule benzene-1,4 - dithiol is chosen to structure molecular junctions , and the metal electrodes are presumed to be made up of gold .
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该反应具有无金属催化、产率高、操作简单、不需要任何添加剂、避免了传统的硫化试剂&硫酚(醇)等恶臭原料的使用等优点。
The important features of the methodology are metal-free catalyst , high yields , simple operation , and no requirement for additive and avoiding the use of odor substrates such as thiols .
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利用模型化合物对甲苯硫酚,借助于气相色谱和质谱等分析手段,探讨了硫醇的氧化行为以及烃类化合物和其它非烃化合物对硫醇氧化性能的影响,并初步推断其可能遵循的反应机理。
The objective of this paper is to study the oxidation of thiols in FCC diesel and the mechanism of its effect on the stability of diesel by GC and GC-MS analyses .
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以廉价易得的硒为催化剂,一氧化碳为羰基化试剂,首次系统地研究并实现了苯胺、芳香硝基化合物分别同硫醇或硫酚的羰基化反应。
Using cheap and facile selenium as catalyst , carbon monoxide as carbonylation agent , carbonylation of thiols or aryl thiols with aniline and with nitroarenes has been studied systematically and realized for the first time .
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以邻氯苯甲酸和对异丙基苯硫酚为原料,以十氢化萘为溶剂,在185&190℃,碱性条件下合成了邻苯甲酸对异丙基苯硫醚,产率可达95%,纯度达98%
O-benzoic acid-p ′ - isopropyl phenyl sulfide is synthesized by the reaction of o-chlorobenzoic acid with p-isopropyl thiophenol in the strong basic solution . The productivity of the topic compound is 95 % under proper experimental conditions .