苯乙酮

4-（N，N-二乙基胺基）苯乙酮的制备

Preparation of 4 - ( N , N - Diethylamino ) acetophenone

｛RuCl2｛（R）-P-Phos｝（R，R）-DPEN｝催化苯乙酮不对称加氢的研究

Studies on 〔 RuCl_2 { ( R ) - P-Phos } ( R , R ) - DPEN 〕 Catalytic Properties in the Hydrogenation of Acetophenone

重组大肠杆菌不对称还原2-羟基苯乙酮合成（R）-苯基乙二醇

Synthesis of ( R ) - 1-phenyl-1,2-ethanediol by stereospecific reduction of

对氨基苯乙酮与Ni（Ⅱ）的配合物的合成与热色性

Synthesis and Thermochromism of Coordination Compound of 4-Aminoacetophenone and Ni (ⅱ) Chloride

参照弗瑞斯（Fries）重排反应合成了对羟基苯乙酮。

P - Hydroxyacetophenone was synthesized according to Fries rearrangement reaction .

Ru-（S）-BINAP/γ-Al2O3催化剂上苯乙酮及其衍生物的多相不对称加氢反应

Heterogeneous Asymmetric Hydrogenation of Acetophenone and Its Derivatives over Ru - ( S ) - BINAP / γ - Al_2O_3

对氨基苯甲酸乙酯与苯乙酮和芳香醛的Mannich反应

The Mannich reaction of 4 Aminobenzoate with acetophenone and aromatic aldehydes

高的Pd负载量有利于苯乙酮转化率的提高，降低Pd的负载量有利于提高产物的对映选择性；

The conversion of acetophenone increases with an increase of the Pd loading , but the enantiomeric excesses of 1-phenyl ethanol is higher at lower Pd loading .

稀土甲基磺酸盐催化苯乙酮、芳香醛和芳香胺的Mannich反应

Rare Earth Methanesulfonate Catalyzed Mannich Reaction of Acetophenone , Aromatic Aldehyde and Aromatic Amine

2,6-二取代苯乙酮苯腙在多聚磷酸（PPA）存在下的成环反应

Cyclizations of 2 , 6-Disubstituted Acetophenone Phenylhydrazones in the Presence of Polyphosphoric Acid

利用β-环糊精对底物的包络作用，经由Fries重排反应选择性合成了邻羟基苯乙酮。

Using the inclusion action of β - Cyclodextrin with phenyl acetate , 2-Hydroxy-acetophenone was Synthesized via Fries rearrangement reaction .

重组菌在IPTG诱导下进行表达，并对2-羟基苯乙酮进行不对称催化还原。

After the induction of IPTG , the recombinants were applied to conduct asymmetric reduction of 2-hydroxyacetophenone .

双波长RP-HPLC法同时测定茵陈蒿中绿原酸、咖啡酸和对羟基苯乙酮的含量

RP-HPLC simultaneous determination of chlorogenic acid , caffeic acid and 4-hydroxyacetophenone in herb of Artemisia capillaris Thunb . under different UV-vis wavelengths hydroxy acetophenone

催化苯乙酮的不对称氢转移反应，反应2小时转化率可达99%，ee值84%。

The asymmetric transfer hydrogenation of acetophenone could complete in 2 hours , with the conversion of 99 % and ee values of 84 % .

树脂的FT-IR和1H-NMR图谱表明苯乙酮甲基上的α-H与甲醛发生缩聚反应。

The FT-IR and ~ 1H-NMR results showed that the α - H of the methyl of acetophenone reacted with formaldehyde by way of polycondensation .

通过酰基化、Fries重排、氯甲基化和氰化合成2-羟基-3-氰甲基-5-甲基苯乙酮，获得了满意的收率（88.5%）。

The synthesis was accomplished via acylation , Fries rearrangement reaction , chloromethylation and cyanation , and a good yield ( 88.5 % ) was obtained .

3,4-二羟基苯乙酮（DHAP）对离体心肌电活动和机械活动的作用

Effects of 3,4-dihydroxyacetophenone ( dhap ) on Electrical and mechanical activities in isolated myocardium

Yb（OTf）3催化苯乙酮、芳香醛和芳香胺的Mannich反应：三组分一锅法合成β-氨基酮衍生物

Yb ( OTf ) _3 Catalyzed Mannich Reaction of Acetophenone with Aromatic Aldehydes and Aromatic Amines : Three Component One-pot Synthesis of β - Amino Ketone Derivatives

所测定的八种VOCs为苯乙酮，苯酚，三氯甲苯，1,3丁二烯，氯苯，甲醇，三氯代乙烷和二氯甲烷。对氯仿敏感；

The eight VOCs were acetophenone , phenol , benzotrichloride , 1 , 3-butadiene , chlorobenzene , methanol , methyl chloroform and methylene chloride . They were mixed together with very low concentrations .

对合成化合物进行了光谱性能测定，实验结果表明，基态下，分子中恶二唑基团与卟啉基团相对独立，没有相互作用；水杨醛邻羟基苯乙酮缩苯胺类Schiff碱的IR和~1HNMR性质

Results of spectral property study indicate that there is no interaction between porphyrin moiety and oxadiazole moiety in the molecula in ground state . IR and ￣ 1HNMR Spectral Property of Schiff bases from Salicylaldehyde and 2-Hydroxyacetophenone with Aromatic amines

在75℃下，以Cu-HMS为催化剂，O2为氧化剂的纯异丙苯氧化反应，苯乙酮为主要副产物，反应的选择性和转化率都很高。

Both the selectivity and conversion of the reaction were high using Cu-HMS as catalyst and O 2 as oxidant at 75 ℃ . Acetophenone was the main by-product .

苯乙酮双缩硫代对称二氨基脲与CuCl2、NiCl2、CoCl2配合物及其抗癌活性研究

Studies on CuCl_2 , NiCl_2 , CoCl_2 complexes and their anticancer activities of 1 , 5-bis ( acetophenone ) thiocarbohydrazone

CS-MCM-48复合载体固定化脂肪酶催化苯乙酮一锅法还原转酯化拆分反应

One-pot Reduction and Transesterification Resolution of Acetophenone Catalyzed by Lipase Immobilized on MCM-48 Coated Chitosan

分别用AA和合成的前列腺素内过氧化物为底物，研究3,4-二羟基苯乙酮（DHAP）对AA代谢影响的作用机理，结果表明DHAP是一种特异的环加氧酶抑制剂。

In addition , we studied mechanism of action of DHAP on AA metabolism by using AA and prostaglandin endoperoxides as substrates respectively , and results indicated that DHAP is a specific inhibitor of cyclooxygenase .

在磷酸盐缓冲溶液-异辛烷混合溶剂中制备了固定化假单胞菌脂肪酶（PseudomonasCepaciaLipase，PSL）PSL/CS-MCM-48，并用于潜手性苯乙酮一锅法还原转酯化手性拆分反应。

The lipase ( Pseudomonas Cepacia Lipase , PSL ) was immobilized on the CS-MCM-48 in a mixed solvent of phosphate buffer solution and isooctane and used for one-pot reduction and transesterification synthesis of pure enantiomers from prochiral acetophenone .

离子交换法制备的RuCo分子筛载体催化剂，使用后的催化剂上可观察到邻羟基苯乙酮的官能团。

Some functional groups of o-hydroxyl phenyl acetone have been observed by FTIR analysis on RuCo catalyst after reaction .

目的为了合成新的荧光试剂2-羟基苯乙酮缩-2-羧基苯胺（HAFC）并研究其在测定痕量金属铝离子方面的应用。

Aim To synthesize a new fluorescent reagent 2-hydroxyacetophenone-2-formicanil ( HAFC ) and analyse its use in the determination of trace aluminum .

4羟基苯乙酮或2,4二羟基苯乙酮与取代苯甲醛在乙二醇溶液中，以硼酸为催化剂，于110～120℃反应6h，再经柱分离精制得羟基查尔酮衍生物。

Chalcones can be prepared through condensation of 4-hydroxyl acetophenone or 2,4-dihydroxyl acetophenone with substitued benzaldehydes in ethyl glycol solution , using the catalyst of boric acid at 110 ~ 120 ℃ in 6 h. The product was purified by the flash chromatography on silica gel .

本论文以苯乙酮和氯乙酸乙酯为原料，经Darzens缩合、酯基水解、脱羧、氧化反应过程合成了2-苯基丙酸，全合成产率为63.4%，对其工艺过程进行了研究和优化。

In this dissertation , the 2-phenylpropionic acid was synthesized in a total yield of 63.4 % by Darzens condensation , hydrolysis of ester , decarboxylation and oxidation with acetophenone and ethyl chloroacetate as starting materials .

以二氧化硅负载壳聚糖-钯络合物（SiO2-CS-Pd）为催化剂，在常温且氢气压力恒定为1.0×105Pa下，以乙醇为溶剂催化苯乙酮加氢生成1-苯基乙醇，用气相色谱仪跟踪反应进程。

Chitosan-palladium complex ( SiO2-CS-Pd ) is used as catalyst to catalyze the hydrogenation of acetophenone at normal temperature and 1.0 × 105 Pa H2.GC is used to test the reaction course .