络合催化剂
- 网络complex catalyst;DMC;Rh-TPPTS
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因此,采用溶胶-凝胶法包容金属络合催化剂是一种很有发展前途的过程。
So the entrapment of homogeneous metal complex catalysts in sol-gel matrices is a promising procedure .
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采用络合催化剂研制浅色C5石油树脂
Developing of Light Color C_5 Petroleum Resin with Catalyst Complex
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稀土络合催化剂Nd(P204)3-Al(i-Bu)3-H2O的活性中心形成研究
Study on the formation of active species of rare earth coordination catalyst
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本文研究稀土化合物与三异丁基铝组成络合催化剂聚合甲基丙烯酸丁酯(BMA),考察催化剂的组分比、溶剂、不同的稀土元素和配体对聚合的影响。
This paper study on the polymerization of butyl methacrylate ( BMA ) by rare earth coordination catalysts .
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对双金属络合催化剂用于催化合成聚醚的起始条件进行了研究,讨论了起始温度、催化剂用量、PO的起始压力等因素对聚醚质量的影响。
The starting conditions for synthesis of polyether polyols catalyzed by DMC were studied . The effect of starting conditions included starting temperature , amount of DMC and starting pressure of PO on the quality of polyether polyol was discussed .
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采用双金属络合催化剂(DMC)制备具有极低的不饱和度、相对分子量高、分子量分布窄、平均官能度高等特点的新型聚醚多元醇。
In this paper , a double-metal cyanide complex catalyst ( DMC ) was used to prepare a new polyether polyol with very low unsaturation , high equivalent molecula weight , narrow molecular weight distributing , high average functionality , etc.
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采用工业上应用较成功的HC-402-2型镍基均相Ziegler型络合催化剂,在排除扩散影响的条件下,研究了苯均相催化加氢制环己烷的反应动力学。
Reaction kinetics of benzene hydrogenation was studied with HC-402-2 commercial homogeneous Ziegler Ni-base complex catalyst . The experiments were carried out without diffusion effect .
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利用稀土钇的磷酸酯盐和三异丁基铝组成的络合催化剂[Y(P204)3-Al(i-Bu)3]催化CO2与缩水甘油醚类单体(GE)的共聚反应,合成出新型高分子材料脂肪族聚碳酸酯。
And aliphatic polycarbonates were synthesized by copolymerization of CO 2 with GE catalyzed by coordination catalyst composed of Y phosphonate and triisobutylaluminum [ Y ( P 204 ) 3 A1 ( I Bu ) 3 ] .
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铑膦络合催化剂活化过程的原位红外研究
In Situ Infrared Study on Activation Process of Rhodium Phosphine Complex
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丙烯聚合络合催化剂中醚的作用
The action of ether in the catalyst for the propylene polymerization
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新型铜络合催化剂用于羰基合成碳酸二甲酯的工艺过程
Dimethyl carbonate synthesis by oxidative carbonylation with a new Cu-based complex catalyst
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高分子膦-钯络合催化剂的氢化催化活性和稳定性的考察
The activity and stability of polymeric PHOSPHINE-PALLADIUM catalysts for hydrogenation of olefins
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高聚物固载化含氮和含膦配体络合催化剂的制备和催化活性
Catalysts preparation and activity of polymer bound complexes containing nitrogenous and Phosphorous Ligands
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调节剂存在下双金属氰化络合催化剂催化环氧丙烷聚合的动力学
Kinetics of DMC catalyzed polymerization of propylene oxide in the presence of regulators
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镍基均相络合催化剂苯加氢反应动力学研究
Kinetics of Benzene Hydrogenation with Homogeneous Ni-Based Complex Catalyst
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丙烯聚合络合催化剂形成过程的研究
Investigation of the formation of the complex catalyst in the polymerization of propylene
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氢甲酰化反应过渡金属络合催化剂有机膦配体调变效应的理论研究
A theoretical study on electronic and steric effects of phosphorus ligands in homogeneous catalysts
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用红外光谱和碘量法定性、定量测定了四羰基钴钠均相络合催化剂的物化性能。
Preparation of tetracarbonyl cobaltate sodium , an important homogeneous complex catalyst , was studied .
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甲醇羰基合成醋酸反应中铑(Ⅰ)络合催化剂的热稳定性
The thermal stability of RH (ⅰ) complex catalyst in the carbonylation of methanol to acetic acid
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本研究对使用传统的三氯化铝络合催化剂聚合得到的聚α-烯烃合成油进行加氢处理以改善其性能。
In this paper , hydrogenation on PAO which polymerized with traditional aluminium trichloride complex catalyst was studied .
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钯-高分子络合催化剂研究(Ⅱ)&油脂中脂肪酸的氢化选择性
The Study of the High Molecular Palladium Complexing Catalyst (ⅱ) - Hydrogenated Selectivity of Fat Acid in Oil
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本文研究丙烯酸十八酯在环烷酸钕、三异丁基铝催化体系中的聚合特征,聚合动力学和机理。结果表明络合催化剂能以高收率制备高分子量的聚丙烯酸十八酯。
Some characteristics , kinetics and mechanism for the polymerization of octadecyl acrylate with Nd ( anph ) 3-AKi-Bu ) 3 system have been studied .
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以烷基铝和四氯化钛为主的齐格勒-纳塔络合催化剂的乙烯齐聚法在0.5升反应釜合成直链偶碳α-烯烃。
Oligomerization of linear α - olefin was carried out in a 0.5 liter vessel using Ziegler-Natta alkylaluminium and titanium tetrachloride as the main catalyst component .
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经过多年的探索研究,我们发现了新的一类定向聚合稀土络合催化剂。
Since 1963 , we have found a relatively new " family " of coordination catalysts composed of rare earth compound for stereospecific polymerization of conjugated dienes .
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以对-特辛基苯酚和甲醛为原料,选用酸、碱及络合催化剂,合成了结构和性能各不相同的对-特辛基苯酚甲醛树脂。
Through the reaction of p - tert-octyl phenol with formaldehyde under the catalysis of acidic , basic or complex compounds , p-tert-octyl phenol - formaldehyde resin was synthesized .
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此外均相络合催化剂多相化后,由于高分子效应和微环境效应还有可能改善催化剂的催化性能。
Moreover , after the process of the homogeneous phase complex catalyst , ' effect of polymer ' and ' microenvironment effect ' would improve the catalytic ability of the catalyst .
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利用均相催化剂和多相催化剂各自的特点,首次在高比表面大孔硅胶负载金属催化剂上担载水相络合催化剂制备复合负载金属支撑水相催化剂。
Combined catalysts comprising supported metal and supported aqueous phase ( SM SAP ) were prepared by immobilizing the homogeneous catalytic phase in the pores of supported metal catalysts with high surface area .
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对高分子负载络合催化剂、可溶性金属络合物催化剂、高分子保护催化剂、模板聚合物催化剂以及稀土、相分离催化剂等作了较为全面的概括论述。
It was described in the polymer catalyst , dissolvable metal complex catalyst , the catalyst protected by polymer , model polymer catalyst as well as earth and critical phase catalyst , etc. with generalization .
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将壳聚糖(CS)负载到SiO2上得到SiO2-CS,再与Pt配位,制得二氧化硅负载壳聚糖络合铂催化剂(SiO2-CS-Pt)。
Chitosan was supported on the surface of silicon dioxide , and then platinum was coordinated on it to prepare silica-supported chitosan-platinum ( SiO_2-CS-Pt ) heterogeneous catalyst .
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一步法络合型催化剂丙烯聚合反应动力学
Kinetics of propylene polymerization on complex - catalysts