单电子转移
- 网络Single electron transfer;one-electron transfer;single electron transfer set;SET-LRP;SET single electron transfer
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的一个经历一个单电子转移黄素蛋白的例子是与微粒NADPH-细胞色素P450还原酶。
An example of a flavoprotein undergoing a one-electron transfer is with the microsomal NADPH-cytochrome P450 reductase .
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辅酶模型化合物与过硫化物间单电子转移反应机制的新证据
A new evidence for the one-electron transfer between organic disulfides and a model coenzyme of nadh , n benzyl-1 , 4 Dihydronicotinamide
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有机化合物的单电子转移反应(SET)是一个新兴的前沿领域。
Single Electron Transfer ( SET ) reaction is a rising front field .
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第二章,首次将DTA用于自由基聚合反应,提出了DTA还原过程为两步单电子转移,能够引发自由基聚合的机理。
Chapter II : It is the first time that DTA was employed in radical polymerization . A two-step single-electron-transfer process of DTA reductions is proposed to explain the production of free radicals and the initiation .
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二硫化钼润滑失效的单电子转移机理研究
Study on the Electron Transfer Mechanism of MoS 2 Lubricating Failure
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二氧化氯与苯酚的单电子转移反应机理
Mechanism of the single electron transfer between clo_2 and phenol
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氮氧自由基的研究(Ⅺ)&哌啶氮氧自由基与羟胺的单电子转移反应
Studies on Nitroxides (ⅺ) & One-Electron Transfer Reaction of Piperidine Nitroxides with Hydroxylamine
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格氏试剂与酮反应的一个重要途径&单电子转移
A Significant Pathway for the Reactions between Grignard Reagents and Ketones-Single Electron Transfer Process
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配合物单电子转移反应的电子传递系数计算
Calculation of the electronic transmission coefficient for single electron transfer reaction in the coordination compound
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反应可能经锌单电子转移诱发的非链式自由基亲核取代机理。
A non-chain radical anion mechanism induced by single electron transfer from zinc is proposed .
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单电子转移和硝化反应
Single electron transfer and nitration reaction
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硝基苯甲酸酯水解反应单电子转移机理的证据&ESR和自旋捕获的研究
Evidence for Single Electron Transfer Mechanism in the Hydrolysis of Nitrobenzoic Esters ESR and Spin-trapping Studies
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α-氰基苄基碳负离子钠盐与碳酸二乙酯的单电子转移反应动力学和机理
Kinetics and Mechanism of the SET Reaction of α - Cyanobenzyl Carbanion Sodium Salt with Diethyl Carbonate
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单电子转移反应
Single Electron Transfer Reactions
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表明反应可能是单电子转移引发的自由基链式机理。
All the results seem to indicate that the reaction is a radical chain process induced by electron transfer .
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所以,光诱导的单电子转移和随后的氯离子离去导致双游离基,双游离基分子内偶合成环。
Thus , photostimulated single electron transfer in CTC followed by expelling chloride ion leads to a biradical , which couples intramolecularly .
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哌啶氮氧自由基与一些生物小分子,如半胱氨酸、谷胱甘肽、抗坏血酸等,在溶液及胶束中的反应经过动力学研究证明反应的单电子转移机理。
It has been shown through kinetic studies that the reactions between piperidine nitroxides with some biological small molecules , e.g. cysteine , glutathione , ascorbic acid , in solution or micelles proceed by electron transfer mechanism .
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用苯乙烯进行捕获实验只减少3的量而对4无影响。根据实验结果对1的还原性进行了讨论,提出1向2发生单电子转移的反应机理。
Trapping experiment with styrene decreased the amount of S but had no effect on the formation of 4 . The reducing property of 1 is discussed and single electron transfer mechanism for the reaction of 1 With 2 is proposed .
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在酸性溶液中有质子参与电极过程,卡托普利在电极表面发生单电子转移,生成汞(Ⅰ)-硫化合物,该化合物在电极表面有强吸附,并进一步转化成汞(Ⅱ)-硫化合物。
The proton participated in the electrode process of captopril in acidic solution with one electron transfer on electrode surface to form univalent mercury-sulfur compound . The univalent mercury-sulfur compound has strong adsorptive effect on the electrode surface and transfers gradually to divalent mercury-sulfur compound .
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结果表明,硝基苯电化学还原具有单电子反应的特征,1,4-二硝基苯电化学CV图表现为两对可逆的氧化还原峰,其电化学还原过程是两步单电子转移过程。
The results showed that electrochemical reduction of nitrobenzene was provided with the characteristics of single-electron reaction . However , The CV of 1,4-dinitrobenzene showed two coupled redox waves , suggested that 1,4-dinitrobenzene was reversibly reduced in two - step one - electron transfer .