Carbene

Metal Carbene Based Catalytic Reaction for Atom Economy

基于金属卡宾的原子经济性催化反应研究

Study on Quantum Chemistry of the Addition Reaction for Carbene with Cyanic Acid

卡宾与氢氰酸加成反应机理的量子化学研究

New Progress in Synthesis Method of Carbene

碳烯合成方法的新进展

Transition metal - carbene complexes in organic synthesis

过渡金属卡宾络合物在有机合成中的应用

1,4 Addition reactions of carbene to dienes and their application in organic synthesis

卡宾的1,4-加成反应及其在有机合成中的应用

Synthesis of 2 - methyl pentenoic acid with phase transfer catalysis carbene method

相转移卡宾法合成2甲基2戊烯酸

The reaction of tungsten carbene complex from low valent tungsten

低价钨化合物形成钨卡宾络合物的反应研究

Transition-metal-catalyzed decomposition of diazo compounds is an important method to form metal carbene .

过渡金属催化重氮化合物分解是形成金属卡宾的重要手段之一。

Syntheses and Structures of Heterocyclic Carbene & Containing Iron Carbonyl Clusters

含杂环卡宾铁羰基簇合物的合成和结构

Synthesis of α - Amino Acids with Carbene Method through Phase Transfer Catalysts of Phosphonium Salt

季鏻盐相转移催化卡宾法合成α-氨基酸

Recent Progress in Application of N-Heterocyclic Carbene Metal Complexes to Ketone Hydrosilylation

N-杂环卡宾金属配合物在酮硅氢加成反应中的应用新进展

Ab initio study on the addition reaction of carbene with carbon monxide

一氧化碳与卡宾加成反应的从头计算方法研究

Organic-inorganic Hybrid Materials with N-heterocyclic Carbene Metal Complexes : Synthesis , Characterization and Catalytic Application

含氮杂环卡宾金属配合物的有机&无机杂化材料的合成、表征及催化应用

As a new way of polymerization , carbene polymerization has the incomparable advantage compared to traditional addition polymerization .

卡宾聚合作为一种新型的聚合方式，有着传统加成聚合无法比拟的优势。

Synthesis and Application of Precursor of N-Substituted Planar Chiral N-Heterocyclic Carbene

氮杂原子取代的面手性氮杂环卡宾前体的合成及催化应用研究

Ab Initio Study on Transition Metal Carbene Cations

过渡金属卡宾正离子的从头算研究

Asymmetric synthesis of α - methyl - α - amino acids through the phase-transfer carbene method

相转移卡宾法不对称合成α甲基α氨基酸

An Ab Initio Investigation of the Molecular Orbital and Stabilization Energy for Substituted Lithium Carbene Cations

从头计算法研究取代锂卡宾正离子的分子轨道和稳定化能

Application of carbene reactive intermediates in organic synthesis & ⅱ . synthesis of analogy of verbenol

卡宾活性中间体在有机合成中的应用&Ⅱ.马鞭草烯醇类似物的合成

Synthesis of comb-shaped graft copolymers via ring opening metathesis polymerization catalyzed by supported ruthenium carbene complex

载体化络合催化开环歧化聚合合成梳形接枝共聚物研究

Reaction and Application of N-Heterocyclic Carbene

N-杂环卡宾的反应及应用

Studies on Olefin-Coordinating Transition Metal Carbene Complexes & ⅵ . Synthesis and Crystal Structure of Two Novel Inner Salt Complexes of Iron

含烯烃配体的过渡金属卡宾配合物的研究&Ⅵ.两个新奇的铁内盐配合物的合成和晶体结构

A reaction mechanism involving nucleophilic addition of an enamine to a metal carbene and subsequent hydrogen transfer was proposed .

根据这一实验结果和以前对重氮化合物反应机理的了解，我们认为反应的机理是烯胺与金属卡宾首先进行亲核加成，然后发生氢迁移过程，产生烯胺中间体。

N-heterocyclic carbene metal complexes have catalytic activities for many organic reactions , and they are a type of catalyst with potential value .

杂环卡宾金属络合物对许多反应有催化作用，它们是一类有潜在应用价值的催化剂。

Our calculations demonstrate that the mechanism of Rh ( II ) carbene O-H insertion is complicated .

我们的计算从理论上预测了二价铑卡宾插入到O-H，S-H键的反应机理和可能的反应路线，密度泛函计算结果表明Rh（II）-卡宾插入到O-H键的反应机理具有复杂性。

So , the cyclopropane product comes from nickel carbenoids and chromium carbene .

因此，环丙烷化反应产物来源有镍卡宾和铬卡宾。

The Reaction of Tungsten Carbene Complexes with Dichloromethyl Wittig Reagent

卡宾的钨配合物与二氯甲基Wittig试剂的反应

This paper presents the commonness and difference of carbene and silylene by their structures , Preparative methods and chemical properties .

本文主要通过碳烯和硅烯的结构、制备、性质等三方面来阐明它们之间的同和异。

Theoretical ( DFT ) Insights into the Mechanism of Nickel Catalyzed Chromium Carbene Transfer , Cyclopropane and Elimination Reactions

镍催化铬卡宾卡宾转移，环化和消除反应机理的理论研究

Syntheses and Structures of Tris ( Trimethylsilyl ) Cyclopentadienyl Molybdenum Cyclic Carbene Complexes

多（三甲硅基）取代环戊二烯基二羰基钼环卡宾配合物的合成和结构