ATRP

The mechanism of ATRP is introduced briefly in this paper , and the new progresses of ATRP are reviewed , emphasis on the applications of ATRP in copolymer molecular design .

本文对原子转移自由基聚合及其反应机理作了简要介绍，并对其近期进展进行了评述，着重介绍了其在共聚物分子结构设计中的一些应用。

Multiblock copolymers synthesized by ATRP in recent ten years are reviewed .

综述了近十年来采用ATRP技术合成多嵌段共聚物的研究进展。

Progress of Atom Transfer Radical Polymerization ( ATRP ) Applied to the Synthesis of Star Polymers

原子转移自由基聚合（ATRP）在星形聚合物合成中的应用

Atom transfer radical polymerization ( ATRP ) is a new effective method to prepare controlled block copolymers .

原子转移自由基聚合（ATRP）方法是一种新发展起来的可控/活性自由基聚合方法，在合成结构可控共聚物过程中具有广泛应用。

In ATRP and R-ATRP , the research for catalyst system was emphasized .

该类反应中，催化体系是研究的重点和热点。

Atom transfer radical polymerization ( ATRP ) is one of the significant developments of polymer synthesis chemistry recently .

原子转移自由基聚合（ATRP）是近年来高分子合成化学中的重大进展之一。

Star polymers synthesized by atom transfer radical polymerization ( ATRP ) in recent ten years are reviewed .

综述了近10年来采用原子转移自由基聚合（ATRP）法合成星形聚合物的研究进展。

Atom transfer radical polymerization ( ATRP ) has been developed late , but its reaction condition is gentle .

原子转移自由基聚合（ATRP）虽然发展较晚，但是反应条件温和，单体选择范围很宽。

However , for the traditional ATRP , the difficulty to remove catalyst residue after polymerization limits its application in industry .

然而，传统ATRP中，由于催化剂残余难以除去的缺点限制了其在工业上的广泛应用。

The recent application of ATRP in the design and preparation of tailor-made polymers , particular block copolymers , was introduced .

结合最新的研究成果，介绍了ATRP在进行聚合物分子设计尤其是在制备嵌段共聚物方面的进展。

Atom transfer radical polymerization ( ATRP ) is an effective route to synthesize polymers with well-defined structures .

原子转移自由基聚合（ATRP）技术是合成结构规整性聚合物的有效途径。

The Discussion of the Mechanism for the Atom Transfer Radical Polymerization ( ATRP ) Catalyzed by Copper ( Cu ) Complex

铜体系催化原子转移自由基聚合机理研究的讨论

Ionic Liquids as Reaction Media for Polymerization Processes : Atom Transfer Radical Polymerization ( ATRP ) in Ionic Liquids

以离子液体为溶剂的原子转移自由基聚合

The activity of the complex as catalyst in ATRP was confirmed by polymerization of MMA and block copolymerization of styrene .

将该配合物作为催化剂成功地进行了MMA的ATRP反应，和苯乙烯的嵌段聚合，证实该化合物作为ATRP催化剂具有催化活性。

The mechanism of the Atom Transfer Radical Polymerization ( ATRP ) is discussed base on the review of the literature up to data as well as the authors'research results .

在综述现有文献的基础上，结合作者的研究结果，对ATRP的反应机理进行了讨论。

Atom transfer radical polymerization ( ATRP ) and nitroxide-mediated polymerization ( NMP ) were employed to control the macromolecular chain structure efficiently .

本文通过原子转移自由基（ATRP）和氮氧自由基可控聚合（NMP）活性聚合方法有效地控制聚合物分子链结构，合成了一系列具有功能性侧基的活性嵌段共聚物和星形聚合物。

A novel type of functional polymer with designed structure , controlled molecular weight and low polydispersities can be prepared via ATRP ( Atom Transfer Radical Polymerization ) .

通过由对氯甲基苯甲酸引发的苯乙烯原子转移自由基聚合（ATRP）合成了分子量可控、分子量分布窄的新型功能聚合物。

In this thesis , synthesis and properties of elastin graft copolymer via atom transfer radical polymerization ( ATRP ) and thio-iniferters were described .

本论文描述了两种弹性蛋白表面改性的方法：原子转移自由基聚合（ATRP）和硫代-引发转移终止剂（thio-iniferters），并对其性能进行了研究。

NMR characterization of the synthesized products shows that the double bond in the norbornene rig of the product polymers is not affected by the ATRP conducted .

产物的NMR分析证明所合成产物分子中降冰片烯环上双键未参与聚合反应。

Hence , in the dissertation atom transfer radical polymerization ( ATRP ) was adopted for preparation of Fe3O4 / SiO2 / PMMA magnetic polymer microspheres .

本文探索了利用原子自由基聚合（ATRP）进行Fe3O4/SiO2/PMMA磁性高分子微球的合成。

The copolymers that have different incorporations were converted to macromolecular initiators , graft copolymers were synthesized by atom transfer radical polymerization ( ATRP ) .

将插入率不同的共聚物转化成大分子引发剂，通过原子转移自由基聚合合成不同接枝率的主链为聚乙烯的接枝共聚物。

Based on the composition , morphology and function , this dissertation successfully synthesized a series of stimuli-responsive macromolecules by using atom transfer radical polymerization ( ATRP ) or click chemistry .

本论文从分子设计的三要素&组成、形态和功能性出发，利用原子转移自由基聚合（ATRP）和点击化学，成功合成了一系列组成不同、形态各异，且具有不同敏感性的聚合物。

The reaction mechanism , initiators ' composition , catalyst system , monomers suitable for use , polymerization temperature and medium of atomic transfer radical transfer polymerization ( ATRP ) are systematically summarized .

概述了原子转移自由基聚合（ATRP）反应的机理、引发剂的组成、催化体系、适用单体、聚合温度、反应介质的近期研究进展；

The paper reviewed the modification of chitosan by free radical polymerization and atom transfer radical polymerization ( ATRP ), emphasized the application of ATRP on graft copolymerization of chitosan .

综述了普通自由基聚合和原子转移自由基聚合（ATRP）反应对壳聚糖及其衍生物进行修饰改性的研究现状。着重介绍了ATRP技术在壳聚糖接枝改性方面的应用。

Degenerative transfer radical polymerization ( DT ) of MMA with I_2 as a transfer agent and AIBN / I_2 system in situ initiated ATRP of MMA ;

元素碘及其衍生物作为MMA的DT聚合链转移剂以及元素碘与AIBN原位反应产物引发MMA的ATRP；

The status of helical polymer and the synthesis methods are reviewed in this dissertation . The synthesis of optically active helical polymer by the atom transformation radical polymerization ( ATRP ) is carried out .

本文综述了螺旋聚合物的研究历程以及螺旋聚合物的合成方法，开展了原子转移自由基聚合（ATRP）制备单手性螺旋过量聚合物的研究。

Based on the atom transfer radical polymerization ( ATRP ) and the large amount of functional groups of hyperbranched polymers , core-shell multi-arm star polymer brushes with gradient polarity distribution were designed and prepared .

设计并通过原子转移自由基聚合方法（ATRP）合成了核壳型具有梯度极性的多羟基多臂星状聚合物刷。

Amphiphilic block copolymer poly ( ethylene oxide ) - polyacrylonitrile ( PEO-b-PAN ) have been synthesized through the combination of anionic polymerization and atom transfer radical polymerization ( ATRP ) .

结合阴离子聚合和活性自由基聚合方法合成了聚环氧乙烷-聚丙烯腈两亲性嵌段聚合物（PEO-b-PAN）。

Many synthetic approaches such as self-condensing vinyl polymerization ( SCVP ), reversible addition-fragmentation chain transfer polymerization ( RAFT ) and atom transfer radical polymerization ( ATRP ) have been used to prepare branched polymers .

自缩合乙烯基聚合、可逆加成断裂链转移聚合、原子转移自由基聚合等多种方法被用来合成超支化聚合物。

The thesis consists of four parts : Degenerative transfer polymerization ( DT ) of MA with iodide in situ as a transfer agent and AIBN / I_2 / MA in situ initiated atom transfer radical polymerization ( ATRP );

本文由以下四个部分组成：碘原位生成物作为链转移剂的MA的DT聚合；AIBN／I2原位反应物引发St的原子转移自由基聚合（ATRP）；