氨基醇
- 名amino alcohol
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考察了Schiff碱配体的水杨醛单元和氨基醇单元取代基性质对反应活性和对映选择性的影响。
The effects of the substituents on both the salicylaldehyde unit and the amino alcohol unit of Schiff base ligands on asymmetric sulfoxidation were explored .
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樟脑衍生的新手性氨基醇的合成
Synthesis of new chiral amino alcohol derived from camphor
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把氨基酸还原为氨基醇,以其为合成砌块,在室温与4-羟基丁烯内酯经Michael加成/分子内消除反应,合成了标题化合物。
Synthesized the title compound via Michael addition / intramolecularly elimination reaction of 4-hydroxy-butenolides under room temperature using aminoalcohol that was reducted by amino acid as synthetic block .
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邻苯二甲酸酐(PA)与3-硝基邻苯二甲酸酐(NPA)在乙腈、二甲苯溶剂中对α-氨基醇中氨基保护的反应机理
The mechanism of the reactions between phthalic anhydride ( PA ) or 3-nitro phthalic anhydride ( NPA ) with α - amino alcohols in acetonitrile or xylene
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在加入表面活性剂CTAB的条件下,分别讨论了CTAB的吸附及钛氨基醇配合物溶液浓度的影响。
( 2 ) Under the addition of surfactant CTAB , two influence factors are discussed : the adsorption between ZnS phosphors and CTAB , concentration of titanium diethanolamine complex .
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首次报道了新型C10高碳糖胺基衍生物的合成.含高碳糖片断的氨基醇及水解产物的波谱分析
A series of novel C10 higher carbon amino sugar derivatives are synthesized for the first time . Structure Elucidation of A Higher Carbon Sugar-Derived Amino Alcohol and Its Hydrolysate by NMR
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以天然氨基酸为起始原料,经过简单的两步反应合成了β-氨基醇配体3a-3i。
From commercially available starting materials natural amino acid , P-amino alcohol ligands 3a-3i were prepared in two simple steps .
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方法2是在N2保护120~145℃下,多元羧酸与手性α-氨基醇反应3~12h,一步反应合成了目标物,产率为71·2%~95·7%。
Multiple carboxylic acids reacted with chiral α - amino alcohols for 3 ~ 12h within 120 ~ 145 ℃ under the protection of N_2 , and afforded the title compounds in 71.2 % ~ 95.7 % yields via a one-step reaction in the second synthetic method .
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手性氨基醇催化的前手性芳酮的不对称还原反应
Enantioselective Borane Reduction of Prochiral Aryl Ketones Catalyzed by Camphyl Aminoalcohols
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一组新的光学活性脂肪族β-氨基醇的合成
Synthesis of a new series of chiral aliphatic β amino alcohols
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N-烷基化手性氨基醇配体的合成
Syntheses of Chiral Ligands : 1,2-Diphenyl-2 - ( N-alkyl ) amino Alcohols
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葡萄糖衍生的新型光学活性β-氨基醇的合成
Synthesis of New Optically Active Amino Alcohol Derived from D-Glucose
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手性氨基醇是有机合成中一类非常重要的化合物。
Chiral amino alcohols are important compounds in organic synthesis .
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不对称硼烷还原合成手性氨基醇
Synthesis of Chiral Amino Alcohols by Enantioselective Borane Reduction
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手性技术与生物催化手性氨基醇的合成及其催化性能研究
Studies on the Syntheses , Catalytic Activity and Stereoselectivity of Chiral Amino Alcohols
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催化不对称烷基化反应中氨基醇配体研究进展
Progress of Amino Alcohol Ligands in Asymmetric Catalytic Alkylation
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手性氨基醇的合成研究
Study on the Synthesis of Chiral Amino Alcohols
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两种手性β-氨基醇的合成
Synthesis of Two Chiral β - Amino Alcohols
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综述了手性氨基醇作为配体或催化剂在不对称合成中的应用及最新进展。
These chiral amino alcohols were first applied to the asymmetric reduction of acetophenone .
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手性氨基醇用于苯乙酮的不对称还原研究
Study on the Asymmetric Reduction of Acetophenone in the Presence of Chiral Amino Alcohols
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本文主要研究了一种利用氮杂环丙烷开环反应合成邻位氨基醇的有机新反应。
This paper reports a new green ring opening reactions of aziridines with H_2O .
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手性α-氨基醇的N-酰基化
N-amidation of chiral α - amino - alcohol
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由氨基酸酯制备氨基醇
Synthesis of Amino Alcohol from Amino Acid Esters
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聚氨基醇胺类染色织物耐洗色牢度提升剂的合成及应用
Synthesis and application of amino-alkanolamine polymers as washing fastness improvers for dyed silk fabrics
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本文对手性氨基醇的应用和制备进展进行了较全面的论述。
The comprehensive review about the application and preparation of chiral amino alcohols was reported .
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两种新型手性氨基醇的合成
Synthesis of Two Novel Chiral Amino Alcohols
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一种改进的制备手性氨基醇的方法
An Improved Procedure for Preparing Chiral Aminoalcohols
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手性β-氨基醇的合成及其在不对称加成和环氧化反应中的应用
The Synthesis of Chiral β - amino Alcohols and Their Application in Asymmetric Addition and Asymmetric Epoxidation
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含硫手性β-氨基醇的合成及其在对映选择性还原反应中的应用
Synthesis of Sulfur-Containing Chiral β - Amino Alcohols and Their Application in the Enantioselective Reduction of Prochiral Ketones
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然后酚羟基保护后的β-氨基醇与二茂铁甲酰氯反应,经过关环形成嗯唑啉。
And then the phenolic hydroxyl group protected β - amino alcohols reacted with ferrocene chloride and then cyclized forming the oxazolines .