四苯基卟啉

四苯基卟啉及其衍生物的表面光电压谱

The surface photovoltage spectra of TPP and its derivatives

针对上述两个问题，本文通过改变四苯基卟啉锌苯环上的取代基，来考察取代基对卟啉锌荧光强度和电致发光性能的影响；

Based on above two problems , we investigate the influence of different substitutes of tetraphenylporphyrin zinc on fluorescent intensity and electroluminescent performances .

法拉第参数对几种四苯基卟啉金属络合物MCD谱的影响

Effect of the Faraday parameters on the MCD spectra of metalloporphyrin

利用表面光电压谱（SPS）研究了四苯基卟啉及其衍生物的表面光伏性质。

The surface photovoltaic properties of TPP and its p-phenylsubstituted and metallo derivatives were studied by the surface photovoltage spectroscopy ( SPS ) .

以荧光光谱和1HNMR谱研究了驱动四苯基卟啉锌（Ⅱ）[Zn（TPP）]咪唑基尾式卟啉铁（Ⅲ）[Fe（pImEPTPP）Cl]超分子自组装的配位键。

Coordination bonding driving supramolecular self-assembly of Zn ( TPP ) with Fe ( p - ImEPTPP ) Cl was investigated by fluorescence spectra and ~ 1H NMR .

质量分数65%的浓硝酸与硝基四苯基卟啉（TPP）反应较完全且没有副产物生成，单硝化TPP（m-NTPP）的收率达到约80%；

The yield of mono nitro TPP reaches 80 % through the reaction of 65 % concentrated nitric acid and TPP , and little byproduct is found .

Horrocks，Jr。法合成和纯制了12个稀土乙酰丙酮-α，β，γ，δ-四苯基卟啉络合物，并讨论了它们对热、空气以及水和有机溶剂混合液的稳定性。

Stability of these complexes to heat , air and water-organic solvent mixture was discussed .

在酞菁氧钛（TiOPc）和四苯基卟啉氧钒（VOTPP）复合光生材料中发现在蓝光区表现出显著的光电导性能协同增强效应。

A synergetic enhancement in photosensitivity of TiOPc / VOTPP composite photogeneration materials was found under the illumination of blue light .

在四苯基卟啉的合成中，对Adler法进行了改进，采用对硝基苯甲酸代替丙酸作催化剂，并采用二甲苯为溶剂，通过分水，成功合成了四苯基卟啉。

Tetraphenylporphyrin ( TPP ) is synthesized successfully by using 4-nitrobenzoic acid as the catalyst and xylene as the solvent based on Adler . Ethyl 4-nitrobenzoate (ⅰ) was prepared in 81.1 % yield by reaction of 4-nitrobenzoic acid with anhydrous ethanol in the presence of 98 % sulfuric acid .

苯酚锰（Ⅲ）四苯基卟啉配合物的合成、光谱性质和催化加氧反应

Synthesis , spectral properties and catalytic oxidation of tetraphenylporphyrinatomanganese (ⅲ) phenolate

合成四苯基卟啉及其衍生物的新方法

A New Synthetic Method for TPPH_2 and It 's Derivatives

具有不同长度碳链的不对称四苯基卟啉及其金属配合物的合成

The synthesis of unsymmetrically substituted porphyrins and their metal complexes

对位单取代缬氨酸四苯基卟啉锰催化氧化烃类的研究

Studies of Hydrocarbons Oxidation Catalyzed by Para monosubstituted Valine Tetraphenyl porphyrin manganese

不同第六轴向配体的苯酚锰（Ⅲ）四苯基卟啉配合物的研究

Study of various axial - ligand complexes of phenolate manganese (ⅲ) tetraphenylporphyrinate

一种估算激光等离子体中气体反应温度的方法四苯基卟啉的激光等离子体质谱研究

Preliminary Research on Temperature Estimation of Laser Plasma Gaseous Reactions by Thermodynamic Method

迭氮基吡啶四苯基卟啉合铬（Ⅲ）的合成及晶体和分子结构

Synthesis , crystal and molecular structures of azido chromium (ⅲ) tetraphenylporphyrin pyridine complex

氨基取代四苯基卟啉衍生物的结构剖析

Structural Analyses of Tetraphenyl Porphyrin Derivatives with Amino Substituents

铁表面四苯基卟啉蒸汽沉积膜形成和结构研究

Formation and structure of vapor deposited ( tpp ) h 2 film on iron

乙酰丙酮稀土四苯基卟啉配合物的电化学研究

Electrochemical Study on Acetylacetone-Tetraphenyl Porphyrin Rare Earth Complexes

对于光敏剂的研究主要集中在四苯基卟啉类化合物及其金属络合物，由于激发波长短，对动物组织穿透能力差，不能用于深层肿瘤的治疗。

The study of photosensitizer was mainly on tetraphenyl porphyrins and its metal complex .

卟啉化合物的研究ⅩⅢ.取代四苯基卟啉蒽醌化合物的合成和光谱性质研究

Study on porphyrin compounds xiii . synthesis , structure and spectral property of p-aq compounds

取代四苯基卟啉蒽醌化合物的合成、结构和光物理性质

Synthesis and Photo-physical Properties of P-AQ Compounds

OH~-存在下四苯基卟啉合钴氧化过程的电化学和光谱电化学

Electrochemistry , Spectroelectrochemistry of ( TPP ) Co in the Presence of OH - Anions

四苯基卟啉质子化结构变化的理论研究（Ⅱ）&五氟苯基及吡咯环上氟的取代基效应

Theoretical Studies on the Structural Change of the N-Protonated Tetraphenylporphyrin (ⅱ) The Effects of the Substituting Groups Fluorines

介绍了用四苯基卟啉铝络合物催化体系合成高分子量聚醚的方法。

This paper introduces the synthesis of the high molecular weight polyether by using metalloporphyrin complex catalyst system .

影响间位取代四苯基卟啉锌轴向配合物稳定因素的研究

A Study of the Effect on the Stability of Axial Complex of meso Tetra ( m substituted ) phenylporphyrin Zinc

微波对四苯基卟啉的合成存在非热效应，可提高反应试剂缩合关环形成四苯基卟啉的速率。

Microwave inducement resulted in the athermal effect , which can increase the velocity of close_loop condensation reaction in the formation of TPP .

实验表明，四苯基卟啉锌/甲苯溶液具有良好的光限制特性，并且具有较低的限制阈值，是一种具有较大潜在应用价值的新型光限制材料。

The experimental results show that the material displays good optical limiting performance . And the critical value of optical limiting is very low .

结果表明，在四苯基卟啉的苯基上的氢被羟基取代后的化合物能增强光电效应。

It has been shown that the photoelectrochemical properties of tetraphenyl-porphyrin with hydroxyl group on phenyl group was increased and that with methoxy group was decreased .

目前，催化氧化反应中所涉及到的卟啉类催化剂大都是人工合成的四苯基卟啉衍生物，催化活性较低，产物选择性较差。

At present , the porphyrin catalysts involved in catalytic oxidation reactions are mostly based on tetraphenyl-porphyrin derivatives achieved by artificial synthesis , which owns low catalytic activity and poor selectivity .