反应速率常数

流动放电&化学发光法测定O（~3P）和C2H1反应速率常数

Determination of the Rate Constant of Reaction of O ( 3 ~ p ) With G_2H_4 by Discharge Flow-chemiluminescence

O（~3P）原子与3-戊酮反应速率常数与温度关系的测定

The determination of the dependence of the rate constant of reaction between o ( ~ 3p ) and 3-pentanone on temperature

碱金属原子和OH三级反应速率常数研究

Rate Constants of Termolecular Reactions of Alkali Atoms with OH

pH由5.6升高到9.8，氧化反应速率常数提高11.8%。

PH increased from 5.6 to 9.8 , oxidation rate constant increased by 11.8 % .

蔗糖酸催化转化反应速率常数k，一些文献认为是一个复合常数，本研究应用实验的k与C（H~+）关系数据作图时，发现k与C（H~+）为指数关系。

In some references , the rate constant k of sucrose inversion reaction was a compound constant .

用Excel处理二级反应速率常数测定的数据

Processing Involved Data in the Experiments of Determining Rate Constants for Second-order Reaction with Excel

采样极谱法测定SOD模型化合物催化超氧离子歧化反应速率常数

The Determination of Dismutation Rate Constant of Superoxide Ion Catalyzed by SOD Model Compound with Tast Polarography

目的：测量铂化金属硫蛋白（Pt7Th）与羟自由基（OH·）的反应速率常数。

OBJECTIVE : To determine the rate constants of the reaction of Pt 7 thionein ( Pt 7Th ) with hydroxyl radicals .

研究25℃时，S（Ⅳ）在模拟雨水中的催化氧化反应速率常数随pH值变化的关系。

The relation of the aqueous S (ⅳ) catalytic oxidation rate constant to pH was studied at 25 ℃, the mathematical model was established .

把反应速率常数和量子产率作为动力学常数，研究了石油烃类化合物的TiO2光催化氧化降解。

The reaction kinetics constants and quantum yields of petroleum hydrocarbons by TiO_2 photocatalytic oxidation were studied .

研究电导法测定溶液中二级反应速率常数k的计算方程。

In this paper , the equations of the method of electric conductance determination of kinetics of second order reaction in solution were studied .

H2O2分解反应速率常数测定过程中用加热升温法测定V∞值的可靠性

Subject The Determination of Reliability of V_ ∞ by Heating in the Experiment of Determining the Rate Constant of H_2O_2 Decomposition Reaction

本文探讨了该薄膜电极的电化学行为，测定了该体系的电化学参数如电荷传递扩散系数D（ct）和非均相电极反应速率常数k等。

The electrochemical parameters , such as charge transport diffusion coefficient , Dct , and heterogeneous electrode reaction rate constant , k ' , were determined .

AsO2~-催化下CO2在碳酸盐缓冲溶液吸收反应速率常数的测定

The Determination of Reaction Rate Constant of Carbonate Buffer Solution Absorpting CO_2 under AsO_2 ~ - Catalysis

钝化反应速率常数的升高会导致体系Pw与PI的降低。

The higher deactivation rate constant is , the lower Pw and PI are .

认为，影响蔗糖分解反应速率常数K的显著因素是pH、温度以及二者的交互作用；

It is found that there is a remarkable influence of pH , temperature and their mutual effects on the rate constant K of sucrose decomposition .

根据此模型所拟合出的反应速率常数k，平衡常数K、扩散系数D和样品表面乙二醇浓度C（？）

Reaction rate constant k , equilibrium cons-tant K , diffusion coefficient D and ethylene glycol concentration on sample surfaceC_s found according to the model are basically constants .

甲醛光催化反应速率常数k随初始浓度、催化剂投加量和光强的增加而增大，随溶液pH值的增加而减小。

The k increases with the increase of initial concentrations 、 catalyst dosage and light intensity . The k decreases with the increase of solution pH value .

用分光光度法测定在氯化钠水溶液中的热反应速率常数和低pH下的速率常数，探讨其反应和酸催化机理。

The thermal reation rate constant for carboplatin in different solvent was worked out , and the thermal substitution of carboplatin-NaCl aqueous solution and its mechanism by acid was also discussed .

测得不同条件下的反应速率常数k，建立了KGM的酸水解动力学方程。

The reaction rate constant K was measured under different conditions , and the acid hydrolysis kinetics equation of KGM was established .

几种气相烷烃自由基与分子Cl2反应速率常数的ACM理论计算

ACM theoretical calculation of the rate constants for the reactions of some alkyl radicals with molecular chlorine in gas phase

推导了电子撞击N2和O2的反应速率常数计算公式，建立过程动力学模型，用matlab编程求解，进行计算机模拟。

Formula of reaction rate constant for electron impacting N_2 and t O_2 is derived . A kinetic model is established , it is soluted with matlab programming , and carried on computer simulation .

提出了从实验数据计算化学反应速率常数和SO2反应级数的新方法，得出的反应级数为0.745。

Meanwhile , a new method of calculating chemical reaction rate constant and reaction order of SO2 was proposed and the value is 0.745 .

渣中FeO还原反应速率常数与泡沫渣的最大发泡高度存在很好的相关性，还原速度增加，泡沫渣的最大发泡高度也随之提高。

The maximum slag foaming height increases with the increase of reaction rate constant of FeO reduction .

实验结果表明，在25℃时，葡萄糖可以在好氧条件下作为共代谢基质使TCE发生生物降解，其一级反应速率常数为03212d-1，半衰期为216d；

Results indicate that glucose can serve as a primary substrate and enhance TCE biodegradation under aerobic cometabolism ;

结果（1）曲克芦丁在100℃时的反应速率常数k为4.82×10-2d-1，t0.9为2.2（d）。

Results ( 1 ) The reaction rate constant is 4.82 × 10-2d-1 and to . 9 is 2.2 days .

将计算区划分成6个区，计算出αi、βj及化学反应速率常数kj，求得各分区的K值。

In order to calculate α _ I 、β _ j and chemical reaction 's rate constant and calculate K in each subzone , the authors divide the area into six parts .

本文采用田晴夫等提出的改良型湿壁塔作为测定NH3&CO2反应速率常数的实验装置，进行了碳化氨水溶液对CO2吸收速率的测定。

Using the improve wet wall tower measure the reaction velocity coefficient of NH_3-CO_3 . The thesis shows that the NH3 · H2O in low carbonization absorb CO_2 is one step fast reaction pattern ;

建立了反应速率常数与温度间关系的方程，由此方程可预测出存放一定时间后DDS的质量分数变化情况，对生产有一定指导意义。

The equation of the relationship between reaction rate constant and temperature was established . The change of mass fraction of DDS was forecasted by the equation after a time stored .

100℃时的反应速率常数为0.0280min-1，表观活化能为36.22kJ/mol，可用于环境水样中Fe（Ⅲ）的测定。

The speed constant of the reaction at 100 ℃ is 0.028 0 min-1 and the apparent activation energy is 36.22 kJ / mol. The method has been used to determine Fe (ⅲ) in water samples with satisfactory results .